摘要
For addressing the critical problems in current collectors in the aluminium batteries,a variety of carbonbased current collectors,including carbon fiber textiles and three-dimensional(3D)biomass-derivative carbon(BDC)networks,are employed for serving as lightweight non-metal current collectors.The results indicate that all the carbon-based current collectors have electrochemical stability in the acidic electrolyte environments.In the assembled aluminium batteries with all-carbon positive electrodes,thermal annealing process on the carbon-based current collectors has substantially promoted the entire electrochemical energy storage performance.Additionally,both the structure configuration and chemical components of the current collectors have also great impact on the rate capability and cycling stability,implying that the 3D BDC networks are more favorable to offer promoted energy storage capability.Implication of the results from suggests that the carbon-based current collectors and all-carbon positive electrodes are able to deliver more advantages in energy storage behaviors in comparison with the traditional positive electrodes with metal Mo current collectors.Such novel strategy promises a new route for fabricating highperformance positive electrodes for stable advanced aluminium batteries.
For addressing the critical problems in current collectors in the aluminium batteries, a variety of carbonbased current collectors, including carbon fiber textiles and three-dimensional(3D) biomass-derivative carbon(BDC) networks, are employed for serving as lightweight non-metal current collectors. The results indicate that all the carbon-based current collectors have electrochemical stability in the acidic electrolyte environments. In the assembled aluminium batteries with all-carbon positive electrodes, thermal annealing process on the carbon-based current collectors has substantially promoted the entire electrochemical energy storage performance. Additionally, both the structure configuration and chemical components of the current collectors have also great impact on the rate capability and cycling stability, implying that the 3D BDC networks are more favorable to offer promoted energy storage capability. Implication of the results from suggests that the carbon-based current collectors and all-carbon positive electrodes are able to deliver more advantages in energy storage behaviors in comparison with the traditional positive electrodes with metal Mo current collectors. Such novel strategy promises a new route for fabricating highperformance positive electrodes for stable advanced aluminium batteries.
基金
Financial support from National Key R&D Program of China(Grant No.2018YFB0104400)
the National Natural Science Foundation of China(Grant Nos.11672341,11572002 and 51874019)
Innovative Research Groups of the National Natural Science Foundation of China(Grant No.11521202)
National Materials Genome Project(Grant No.2016YFB0700600)
Beijing Natural Science Foundation(Grant Nos.16L00001 and 2182065).