摘要
随着原油重质化趋势加剧,微孔结构Y型分子筛作为催化剂活性组分,不但限制大分子物质在孔道内的吸附,而且易形成积碳,加速催化剂失活。因此,Y型分子筛的介孔改性研究被广泛关注。综述了近年来有关Y型分子筛的不同介孔改性方法,指出各种方法的优缺点。就目前发展来看,脱铝仍是介孔改性的主要研究方向。
The limited dimensions of the micropores of zeolite Y strongly hinder the diffusion of large molecules and this drawback seriously accelerate the catalyst deactivation in the reaction. Therefore, research on Y zeolite mesopore-modification has drawn the attention of many people. In this review, different methods of mesoporemodification of Y zeolite in recent years were summarized, and their advantages and disadvantages were pointed out. In terms of current development, dealuminization for mesopore-modification is still the main research direction.
作者
王天昀
段宏昌
谭争国
张海涛
高雄厚
杜正银
WANG Tian-yun;DUAN Hong-chang;TAN Zheng-guo;ZHANG Hai-tao;GAO Xiong-hou;DU Zheng-yin(College of Chemistry and Chemical Engineering,Northwest Normal University,Gansu Lanzhou 730070,China;PetroChina Lanzhou Petrochemical Research Center,Gansu Lanzhou 730060,China)
出处
《当代化工》
CAS
2019年第11期2709-2712,共4页
Contemporary Chemical Industry
关键词
Y型分子筛
介孔改性
合成
复配
脱硅
脱铝
Y zeolite
Mesopore-modification
Synthesis
Compounding
Desiliconization
Dealumination