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X射线荧光光谱测氧法分析铝电解质分子比 被引量:2

X-ray fluorescence spectrum based on oxygen measurement to analyze the molecular ratio of aluminum bath
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摘要 本文分析了铝电解质成分及分子比在铝工业生产中的重要性,指出了当前基于传统荧光光谱分析检测电解质分析曲线测量电解质分子比存在的不足。为此,探讨了测氧法分析电解质成分的技术改进内涵、光学原理及快速检测的优势,给出了分子比的计算公式;并开展了测氧法分析电解质成分与郑州有色金属研究院有限公司送样的比对验证试验。对比试验与工业批量检测结果均表明本文阐述的测氧检测技术效果良好、与工艺吻合度高。 This paper analyzes the importance of aluminum bath composition and molecular ratio in aluminum industrial production, and points out the drawbacks of current bath molecular ratio measurement based on traditional fluorescence spectrum to analyze the bath analysis curves. Therefore the technical connotation, optical principle and quick detection advantages of the oxygen measurement method to analyze the bath composition are discussed, and the calculation formula of the molecular ratio is presented. The comparison verification between the oxygen measurement method for analyzing the bath composition and the laboratory analysis from the Zhengzhou non-ferrous metals research institute Co., Ltd., of CHALCO is carried out. The comparative test and industrial batch test results show that the oxygen measurement technology described in this paper has a good effect, which coincides well with the process as well.
作者 涂槐 刘四川 秦剑锋 王先国 姚立忠 Tu Huai;Liu Sichuan;Qin Jianfeng;Wang Xianguo;Yao Lizhong(Chongqing Tiantai Aluminum Co.,Ltd.,Chongqing 401420,China;Chongqing Kerui Analytical Instrument Co.,Ltd.,Chongqing 401331,China;School of Electrical Engineering,Chongqing University of Science and Technology,Chongqing 401331,China)
出处 《轻金属》 北大核心 2021年第2期51-55,共5页 Light Metals
基金 国家自然科学基金(No.51805059) 重庆市基础研究与前沿探索(cstc2018jcyjAX0350)项目资助
关键词 电解铝 分子比 测氧法 电解质 electrolytic aluminum molecular ratio oxygen measurement bath
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  • 1邱竹贤.工业铝电解质分子比的演变与现状[J].中国有色金属学报,1996,6(4):13-18. 被引量:13
  • 2段淑贞 乔芝郁.熔盐化学-原理和应用[M].冶金工业出版社,1990..
  • 3Kvande H. Bath chemistry and aluminium cell performance-facts, fictions, and doubts [J]. JOM, 1994, 11:22 - 30.
  • 4Feret F R. Characterization of bath electrolyte by X-ray fluorescence [ A]. Light Metals [ C ]. Warrendale,USA: TMS, 1991. 697-702.
  • 5QIU Zhu-xian. ZHANG Jin-sheng, KAI Grjotheim, et al. Phase equilibrium studies on the cryolite-aluminium fluoride system [ A ]. Light Metals [ C ]. Warrendale, USA:TMS, 1991. 315-320.
  • 6QIU Zhu-xian, ZHANG Jing-sheng, SUN Ting. Infhinces of additives on the cryolite ratio of aluminium electrolyte[A]. Light Metals [ C ]. Warrendale, USA: TMS,1993. 291-295.
  • 7Grjotheim K, Welch B. Aluminium Smelter Technology[M]. German: Aluminium-Verlag GmbH, 1988. 284 -286.
  • 8Danek V, Gnstavsen φ T, Stvold φ T. Structure of the MF-AlF3-AI2O3 ( M-Li, Na, K) melts [J]. Canadioan Metallurgical Quarterly, 2000, 39(2): 153 - 162.
  • 9Haupin W. Defining bath ratio in the presence of LiF and MgF2 [ A ]. Light Metals [ C ]. Warrendale, USA: TMS, 1996. 219-220.
  • 10周铁托,洪建中,殷恩生,潘玉星,刘永刚.铝电解低分子比控制过程中若干技术问题探讨[J].轻金属,1997(10):38-42. 被引量:8

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