摘要
使用化学气相输运法(CVT)制备了高质量Sc掺杂SiP晶体,并探究了Sc掺杂对SiP HER活性的影响。结果显示,掺杂Sc后的SiP具有更优异的HER性能,在电流密度为10 mA/cm2时的过电位为112.8 mV,Tafel斜率为85.09 mV/dec,电化学活性表面积为245 cm2,并具有优异的稳定性。该研究为开发具有高效活性的新型催化剂在HER和其他储能领域的应用提供了深入的见解。
In this study,high-quality Sc-doped SiP crystals were synthesized using the chemical vapor transport(CVT)method,and the influence of Sc doping on the HER activity of SiP was investigated.The results indicate that Sc-doped SiP exhibits superior HER performance,featuring an overpotential of 112.8 mV at a current density of 10 mA/cm2,a Tafel slope of 85.09 mV/dec,an electrochemical active surface area of 245 cm2,and remarkable stability.This research provides valuable insights into the development of novel catalysts with highly efficient activity for applications in HER and other energy storage fields.
作者
刘颖
于童
陆鑫
孙江
LIU Ying;YU Tong;LU Xin;SUN Jiang(School of Mechanical Engineering,Tianjin Renai College,Tianjin 301636;Hitech(Tianjin)Industry Co.,Ltd.,Tianjin 300350;Tianjin Tianfa Main Factory Mechanical and Electrical Equipment Co.,Ltd.,Tianjin 300404)
出处
《机械设计》
CSCD
北大核心
2024年第S02期110-113,共4页
Journal of Machine Design
基金
天津市教委科研计划项目(2023KJ264)
关键词
储能材料
电催化析氢反应
化学气相输运法
Sc-SiP阴极催化剂
energy storage materials
electrocatalytic hydrogen evolution reaction
chemical vapor transport method
Sc-SiP cathode catalys