烯丙基-1,1-偕二醇二醋酸酯作为a^(1)、a^(3)合成子的研究——合成双环[3.3.1]壬烷-9-酮衍生物的简便方法及其反应机理

Allylic Geminal Diacetates as a^(1),a^(3) Synthon——A Convenient Synthesis of Bicyclo[3.3.1]nonan-9-one Derivatives and its Mechanism

本文报道了钯催化下,从烯丙基-1,1-偕二醇二醋酸酯和N-(1-环己烯)-四氢吡咯反应一步合成2-乙酰氧基双环[3.3.1]壬烷-9-酮衍生物的简便方法,并且对可能的反应机理进行了讨论.

2-Acetoxy bioyclo[3.3.1]nonan-9-one derivatives could be synthesized from thereaction of allylic-1,1-diol diacetates with pyrrolidine enamine of cyclohexanone underthe catalysis of palladium complex in one step.The possible mechanism of this novelreaction is discussed.