探究氧化铜等物质催化次氯酸钠分解的反应机理

Inquiry on Reaction Mechanism of NaClO Decomposition Catalyzed by CuO

查阅文献可知,NaClO的分解反应与KClO3的热分解反应极其相似;那么作用于KClO3热分解反应的催化剂(如MnO2,CuO等物质)是否对NaClO分解反应也同样有效呢?实验研究表明,CuO等物质催化NaClO分解反应的效果非常显著。由于NaClO分解反应的温度明显低于KClO3热分解反应的温度,这使我们有可能在低温条件下寻找到NaClO与催化剂反应的中间产物,从而为探究NaClO在催化剂作用下的反应历程获得有力的证据。

According to the literature report,the decomposition reaction of NaClO and KClO3 is very similar.Whether the catalyst such as MnO2 and CuO for the decomposition reaction of KClO3 has similar effective for NaClO?The experimental results show that CuO has a significance catalytic effective for the decomposition of NaClO.In order to explore the reaction process of NaClO at the existence of catalyst,lower pyrolysis temperature of NaClO makes it possible to find the middle products at a relative lower temperature condition.