共轭微孔聚合物结构调整及其荧光发射探究用于吸附传感

Conjugated Microporous Polymer Structure Adjustment and Its Fluorescent Launch Exploration for Adsorption and Sensing

有机多孔聚合物(POPs)是一类高比表面积,具有复杂孔径结构,可修饰不同官能团的新型有机材料,其复杂的微观结构使其在吸附分离领域具有良好的前景。共轭微孔聚合物(CMPs)是有机多孔聚合物的一种,其也具有上述所说的有机多孔聚合物的特性,相比其他类型的有机多孔聚合物,大共轭环的骨架使其结构更加刚性,并赋予其具有可见光区荧光的特性。本工作从调整聚合物合成单元方式调节结构,探究不同类型聚合物的荧光波长,有助于了解其在化学吸附与传感领域的应用。

Porous organic polymers(POPs)are a type of high-ratio surface area with complex pore-diameter structure.It can modify new organic materials with different official groups.Its complex micro-structures give it a good prospect in the field of adsorption and separation.Conjugated microporous polymer(CMPS)is a type of POPs.It also has the characteristics of the organic polymer mentioned above.Compared with other types of POPs,the skeleton of the CPC ring makes its structure more rigid and gives them the characteristics of visible light zone fluorescence.This work regulates the structure from adjusting the polymer synthesis unit to explore the fluorescent wavelength of different types of polymers,which helps discuss its application in the field of chemical adsorption and sensing.