摘要
Methane(CH_(4))holds great promise in replacing oil as a building block for chemical commodities[1].However,due to the low-polar nature and high C-H bond energy(439 kJ/mol)of CH_(4),the conversion of CH_(4)by traditional thermocatalysis requires harsh reaction conditions(e.g.high temperature and high pressure)and thus,is energy-consuming[2].To be worse,the production of undesired products like CO_(2)is unavoidable as a result of hydrocarbon combustion reactions[2].
基金
support from the Program from Guangdong Introducing Innovative and Enterpreneurial Teams(2019ZT08L101 and RCTDPT-2020-001)
the University Development Fund(UDF01001159)
the National Natural Science Foundation of China(No,1805234,22075240,and 21972065)
the Young Scientists Fund of the National Natural Science Foundation of China(No.52202306)
the Shenzhen Key Laboratory of Eco materials and Renewable Energy(ZDSYS20200922160400001)
the Shenzhen Natural Science Foundation(GXWD20201231105722002-20200824163747001)
the NSF of Jiangsu Province(No.BK20220006).
