摘要
1.Text Black phosphorus(BP)has sparked immense interests among two-dimensional(2D)nanomaterials since its first mechanical exfoliation from bulk BP in 2014[1].The atoms in BP are not distributed in the same plane,where the lone pair electrons of P atoms are highly reactive,and the structural anisotropy leads to many distinctive physical properties[2,3],like highly anisotropic effective masses and tunable electronic properties[4].Particularly,it possesses thickness-dependent direct bandgap values from 0.3 eV(bulk)to 1.5 eV(monolayer)[5].Owing to its unique structural and electronic properties,BP shows potential applications in electronic or optoelectronic devices[6-8].However,BP is reported to be unstable and easy to decompose in ambient conditions,which hinders its wide applications[9].Layered BP can rapidly transform into oxides,and further degrade into acids or salts within hours[10].Therefore,it is necessary to take some measures to inhibit the degradation of BP.
基金
supported by the National Natural Science Foundation of China(Grant No.21973067,22173067,62022081 and 61974099)
the Natural Science Foundation of Jiangsu Province(BZ2020011)
the Science and Technology Development Fund,Macao SAR(FDCT No.0052/2021/A)
supported by the Fund for Collaborative Innovation Center of Suzhou Nano Science&Technology,the Priority Academic Program Development of Jiangsu Higher Education Institutions.