钯催化的炔烃芳构化反应研究

Palladium-Catalyzed Aromatization of Alkynes

综述了钯络合物催化的炔烃环三聚芳构化反应的历史沿革及最新研究进展,并结合该研究小组的工作,重点阐述了钯催化炔烃 [ 2+2+2 ] 环三聚芳构化、双炔烃、共轭烯炔 [ 4+2 ] 芳构化反应。同时对反应的几种典型催化体系和反应机理,以及该领域的一些前沿热点也作了综述。

The recent progress in palladium-catalyzed cyclotrimerization aromatization of alkynes is reviewed, espercially for the [ 2+2+2 ] cyclotrimerization aromatization of alkynes, [ 4+2 ] aromatization of diynes, conjugated enynes. Meanwhile, some typical catalyst systems and the reaction mechanism, as well as hotspots in this area are described here.