摘要
在低价钛试剂 (TiCl4/Sm)作用下取代苯乙酮肟发生脱肟反应生成酮 ,而在同样条件下 ,二芳酮肟则生成二芳酮。
When substituted phenyl methyl ketoximes were treated with low valent titanium (TiCl 4/Sm) the deoximation reaction giving ketones in high yields took place, whereas in the case of diaryl ketoximes, diaryl ketones, amines or Schiff bases were formed.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2004年第2期216-218,117,共4页
Chinese Journal of Organic Chemistry
基金
江苏省教育厅自然科学基金 (No.0 0 1KJB1 50 0 0 8)资助项目
关键词
低价钛试剂
芳酮肟
脱肟
low valent titanium reagent
aromatic ketoxime
deoximation
