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聚氨酯弹性体结构对热行为的影响 被引量:2

EFFECTS OF THE STRUCTURE OF POLYURETHANE ELASTOMERS ON THEIR HEAT BEHAVIORS
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摘要 指出影响聚氨酯弹性体热行为的结构因素主要是软段的种类、取代基和分子量,以及硬段的扩链剂和二异氰酸酯的种类与浓度。讨论了这些结构因素对聚氨酯弹性体玻璃化温度、结晶熔融温度、熔融热、比热和绝热温升的影响。 This review, cited with 17 references, referred to the major structural factors that affect the heat behaviors of polyurethane elastomers , i.e., the type, molecular weight and substituents of soft segments, as well as the type and concentration of chain extender and diisocyanates for the hard segments. The effects of these factors on the glass transition temperature, the temperature and heat of crystalline melting , the specific heat and adiabatic temperature rising were discussed.
作者 刘树
出处 《合成橡胶工业》 CAS CSCD 北大核心 1989年第6期411-417,共7页 China Synthetic Rubber Industry
关键词 聚氨酯 结构和性能的关系 玻璃化温度 熔点 比热 综述 polyurethane relationship between structure and properties glass transition temperature melting point specific heat review
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  • 1刘树.嵌段聚氨酯弹性体的热行为[J].聚氨酯工业,1987,(1):2-7.
  • 2[1]Nierzwicki W,Wysocka E.Microphase Separation and Properties of Urethane Elastomers.J.Appl Polym Sci,1980,25(5):739
  • 3[2]Leung L M,Koberstein J T.DSC Annealing Study of Microphase Separation and Multiple Endothermic Behavior in Polyether-Based Polyurethane Blocks Copolymers.Macromolecules,1986,19(3):706
  • 4[3]Koberstein J T.Simultaneous SAXS-DSC Study of Multiple Endothermic Behavior in Polyether-Based Polyurethane Blocks Copolymers.Macromolecules,1986,19(3):714
  • 5[5]Seefried C G,JR,Koleske J V.Thermoplastic Urethane Elastomers.Ⅰ.Effects of Soft-Segment Variations.J Appl Polym Sci,1975,19(9):2493~2502
  • 6[7]Seefried C G,J R,Koleske J V.Thermoplastic Urethane Elastomers.Ⅲ.Effects of Variations in Isocyanate Structure.J Appl.Polym Sci,1975,19(12):3185~3191
  • 7[8]Pandya M V,Deshpande D D.Thermal Behavior of Cast Polyurethane Elastomers.J Appl.Polym Sci,1988,35(7):1803
  • 8[9]Lin I S,Gromelskl S J,JR.Polyether Based Polyurethanes:A Study of Diol Curatives.Elastomer and Plastics,1984,16(4):265
  • 9[10]Obert D C,Raymond P.PU Prepolymer Curative Increased Cast Elastomer Hardness and Resilience.Elastomerices,1989,121(12):19
  • 10[11]Seefried C G,J R,Koleske J V,Critchfield F E.Thermoplastic Urethane Elastomers.Ⅱ.Effects of Variations in Hard-Segment Concentration.J Appl Polym Sci,1975,19(9):2503~2513

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