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中国南海侧扁软柳珊瑚中孕甾烷类化学成分的研究(英文) 被引量：3

Pregnane Steroids in Gorgonian Subergorgia suberosa from the South China Sea
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摘要 从南海侧扁软柳珊瑚Subergorgia suberosa的二氯甲烷-甲醇提取物中首次分离鉴定了8个孕甾烷类化合物,经波谱鉴定为3β-O-palmitoyl-pregn-5-ene-20-one-3-ol(1),3β-O-palmitoyl-5α-pregn-20-one-3-ol(2),5α-pregn-1-ene-3,20-dione(3),3β,5α-pregn-20-one-3-ol(4),3β-pregn-5-ene-20-one-3-ol(5),3β,5β-pregn-20-one-3-ol(6),5β-pregn-3,20-dione(7),pregn-4-ene-3,20-dione(8)。其中化合物1,2为新化合物。 Two new steroids,3β-O-palmitoyl-pregn-5-ene-20-one-3-ol (1),3β-O-palmitoyl-5α-pregn-20-one-3-ol (2),together with six known steroids,5α-pregn-1-ene-3,20-dione (3),3β,5α-pregn-20-one-3-ol (4),3β-pregn-5-ene-20-one-3-ol (5),3β,5β-pregn-20-one-3-ol (6),5β-pregn-3,20-dione (7),and pregn-4-ene-3,20-dione (8) were isolated from the CH2Cl2/MeOH extract of the South China Sea gorgonian coral Subergorgia suberosa,and identified on the basis of spectroscopic evidences and by comparison of the data reported.These comp...
作者 漆淑华 苏国琛 张偲
机构地区 中国科学院南海海洋研究所广东省海洋药物重点实验室
出处 《天然产物研究与开发》 CAS CSCD 2008年第1期1-4,共4页 Natural Product Research and Development
基金 This project was supported by the National Natural Science Foundation of China (grant:20502027) Hi-tech Research andDevelopment Program of China( grant:SQ2007AA09Z435255) Science and Technology Foundation of Guangdong Province
关键词 侧扁软柳珊瑚 孕甾烷 甾体 gorgonian Subergorgia suberosa pregnane steroids
分类号 R284 [医药卫生—中药学]
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参考文献10

  • 1Groweiss A,Fenical W,He CH,et al.Subergorgic acid,a no- vel tricyclopentanoid cardio-toxin from the Pacific gorgonian coralSubergorgia suberosa[].Tetrahedron Letters.1985
  • 2Parameswaran PS,Naik CG,Kamat SY,et al.Studies on the secondary metabolites from the Indian gorgonianSubergorgia suberosa:isolation and characterization of four analogues of the cardiotoxin subergorgic acid[].Journal of Natural Products.1998
  • 3Wang GH,Ahmed AF,Sheu JH,et al.Suberosols A-D,four new sesquiterpenes with beta-caryophyllene skeletons from a Taiwan Residents gorgonian coralSubergorgia suberosa[].JNat Prod.2002
  • 4Wang GH,Ahmed AF,Kuo YH,et al.Two new subergane- based sesquiterpenes from a Taiwan Residents Gorgonian coralSub- ergorgia suberosa[].JNat Prod.2002
  • 5Bokesch HR,McKee TC,Cardellina JH,et al.Suberosenone, a new cytotoxin fromSubergorgia suberosa[].Tetrahedron Letters.1996
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同被引文献34

  • 1艾小红,陈亿新,漆淑华.中国珊瑚化学成分与生物活性研究新进展[J].广州大学学报（自然科学版）,2006,5(1):49-56. 被引量：12
  • 2黄晖,李秀保,练健生,杨剑辉,李元超,邹仁林.福建厦门湾和东山湾海域柳珊瑚的物种多样性及其分布[J].台湾海峡,2007,26(1):92-98. 被引量：9
  • 3温燕梅,漆淑华,张偲.南海脆灯蕊柳珊瑚化学成分的研究[J].热带海洋学报,2007,26(1):73-77. 被引量：10
  • 4Zhang W, GuoY W, Ernesto Mollo, et al. Acanthovagasteroids A- D,Four new 19-hydroxylated steroids from the South China Sea gorgonian Acanthogorgia vagae Aurivillius [J ]. J. Nat. Prod., 2004,67 : 2083-2085.
  • 5QI S H,ZHANG S,LI M Y,et al. Complete ^1H and ^13C NMR assignments of three new polyhydroxylated stemls from the South China Sea gorgonian Subergorgia suberosa [ J ]. Magn. Reson. Chem., 2007,45 : 1088- 1091.
  • 6QI S H, ZHANG S, GAO C H, et al. Purine and pyrimidine derivatives from the South China Sea gorgonian Subergorgia sLtberosa [ J ]. Chem. Pharm. Bull., 2008,56(7) : 993-994.
  • 7QI s H, ZHANG S, HUANG H. Purine Alkaloids from the South China Sea Gorgonian Subergorgia suberosa [ J ]. J. Nat. Prod., 2008,71 (4) :716-718.
  • 8LI L, WANG C Y, GUO Y W, et al. Further highly oxygenated guaiane lactones from the South China Sea gorgonian Menella sp [ J ]. Helv. Chim. Acta., 2008,91 : 111-117.
  • 9SUNG P J, CHUANG L F, KUO J, et al. Rtunphellatin A, the first chloride-contairfing caryophyllane-type norsesquiterpenoid from Rumphella antipathies [ J ]. Tetrahedron. Lett., 2007, 48 : 3987- 3989.
  • 10SUNG P J, CHUANG L F, HU W P. Rmnphellatins B and C, two new caryophyllane-type hemiketal norsesquiterpenoids from the Formosan gorgonian coral Rumphella antipathies [ J ]. Bull. Chem. Soc. Jpn. , 2007,80(12) : 2395-2399.

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天然产物研究与开发
2008年 第1期

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