SYNTHESIS AND PROPERTIES OF POLY(AROMATIC DIACETYLENE)S CONTAINING FLUORENE

SYNTHESIS AND PROPERTIES OF POLY(AROMATIC DIACETYLENE)S CONTAINING FLUORENE

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摘要 Novel fluorene-based poly(aromatic diacetylene)s have been synthesized by CuCl-catalyzed oxidative coupling of aromatic diynes.New aromatic diynes 2,7-diethynyl-9,9-bis(triphenylamine)fluorene(M_1)is synthesized by multistep reactions.The structures and properties of the polymers are characterized and evaluated by IR,NMR,TGA,UV, photoluminescence(PL),and cyclic voltammetry analyses.These polymers possess good thermal stability.All the polymers are completely soluble in coammon solvents such as toluene,THF,c... Novel fluorene-based poly(aromatic diacetylene)s have been synthesized by CuCl-catalyzed oxidative coupling of aromatic diynes.New aromatic diynes 2,7-diethynyl-9,9-bis(triphenylamine)fluorene(M_1)is synthesized by multistep reactions.The structures and properties of the polymers are characterized and evaluated by IR,NMR,TGA,UV, photoluminescence(PL),and cyclic voltammetry analyses.These polymers possess good thermal stability.All the polymers are completely soluble in coammon solvents such as toluene,THF,c...

作者彭汉唐本忠

机构地区 Institute of Material Science and Engineering Department of Chemistry Hong Kong University of Science & Technology

出处《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2008年第2期195-201,共7页 高分子科学（英文版）

基金 This project was financially supported by National Natural Science Foundation of China(No.50473034).

关键词 FLUORENE Glaser-Hay reaction Conjugated polymer DIACETYLENE Poly（aromatic diacetylene）s. Fluorene Glaser-Hay reaction Conjugated polymer Diacetylene Poly（aromatic diacetylene）s.

分类号 O631 [理学—高分子化学]

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1刘承美,薛锋,黄树槐.发蓝光材料聚烷基芴的合成和性能研究[J].高分子学报,2003,13(5):734-737. 被引量：4
2LIN Hongzhen, ZHENG Min, YANG Junlin & BAI Fenglian Laboratory of Organic Solids, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China.Carbazole-containing lightemitting polymers:Properties of excited states[J].Chinese Science Bulletin,2003,48(7):637-642. 被引量：1

二级参考文献22

1狄英伟巴晓微 X谢德民王荣顺.功能材料,1998,10:127-137.
2Fukuda M, Sawada K,Yoshino K.J Polym Sci,Part A,Polym Vhem, 1993,31:2465 - 2471.
3Fukuda M, Sawada K, Yoshino K. Jpn J Appl Phys, 1989,28 (8) : 1433 - 1435.
4Ohmori Y,Uchlda Y,Yoshino K.Jpn J Appl PhyB,1991,30(11B) :1941 - 1943.
5Pei Q,Yang Y,J Am Chem Soc, 1996,118:7416 - 7417.
6Yang Y,Pei Q,J Appl Phys, 1997,81(7) :3294 - 3298.
7Rangr M, Leclenrc M.J Chem Soc,Chem Commun,1997,1597 - 1598.
8Ranger M, Rondeau M,Leclerc M. Macromoecules, 1997,30:7686 - 7691.
9Kreyenschmidt M,Klaerner G,Fubrer T, Ashenhurst J,Kazy S,Chen W D,Lee V Y,Scott J C, Miller D. Macromolecules, 1998,31 : 1009 - 1103.
10Lee S H,Tsutsui T.Thin Solid Films,2060,363:76 - 80.

共引文献3

1武卫莉.荧光橡胶的制备及其性能[J].合成橡胶工业,2005,28(6):432-434.
2覃春杨,刘烽,彭波,黄维,韦玮.含空间位阻基团的超支化聚芴的合成、表征及稳定性研究[J].高分子学报,2008,18(6):537-543. 被引量：7
3刘红霞,张业明,朱雅兰,吴风林.9,9-双(丙酸丁酯基)芴的合成及晶体结构[J].精细石油化工,2010,27(1):58-60.

1WANG Jiang-hong, CAO Ya-an, CAO Chang-sheng, SHI Yan-hui SHONG Qing, WANG Li-jun and YAO Jian-nian (Institute of Photographic Chemistry, Chinese Academy of Sciences, Beijing 100101, P. R. China ,Department of Chemistry, Jilin University, Changchun 130023,.Synthesis of a Soluble Diacetylene with Phenylimidazole Ring[J].Chemical Research in Chinese Universities,2000,16(4):324-327.
2Li, TS,Zhang, ZH,Yang, F,Duan, HY,Li, BZ,Tewari, BB.A Facile Procedure for the oxidative Coupling of 2-Naphthol and 2-Naphthalenethiol in Solid State[J].Chinese Chemical Letters,1998,9(7):603-604. 被引量：2
3黄锦凡,倪行,等.Syntheses,Structures and Properties of Some New Compotition Perovskite[J].Chinese Journal of Structural Chemistry,1994,13(5):350-359.
4CHEN Mu-juan ZHOU Song-gen LI Mei LEI Chun-yan XIAO Rui JIANG La-sheng.Synthesis and Characterization of Two [2]Catenanes Based on Phenylene-diacetylene Crown Ethers[J].Chemical Research in Chinese Universities,2013,29(6):1094-1097.
5ZHAO Zhen and YUAN Song-yue(Changchun Institute of Applied Chemistry, Academia Sinica, Changchun. 130022)YU Zuo-long(Chengdu Institute of Organic Chemistry , Academia Sinica, Chengdu, 610015).Deactivation of Ti-La-Li Multicomponent OxideCatalyst for Oxidative Coupling[J].Chemical Research in Chinese Universities,1994,10(4):321-326.
6靖董莲,曾和平,周亚东,王婷婷,袁国赞,欧阳新华.Synthesis and Characterization of 8-Hydroxyquinoline Derivative Containing a Triphenylamine Unit and Its Metal Complexes[J].Chinese Journal of Chemistry,2006,24(7):966-972. 被引量：2
7崔勤.对二氰基二硫纶5,6—二乙炔基菲啰啉镍(Ⅱ)配合物的一点研究[J].新课程学习（中）,2010(12):10-11.
8LU Hai-jun,LI Xiang-gao,WANG Shi-rong,GAO Wen-zheng,WANG Sha-sha.Synthesis and Properties of Novel Luminescent Compounds Containing Triphenylamine and Bipyridine Units[J].Chemical Research in Chinese Universities,2012,28(2):313-318.
9程玥,王小芳,吕蓓,胡怀明.Syntheses,Structures and Properties for Zn~Ⅱ Coordination Polymers Based on a Functional 4'-(3-Pyridyl)-3,2':6',3''-terpyridine Ligand[J].Chinese Journal of Structural Chemistry,2016,35(12):1953-1959.
10ZHANG Zhongqiang,DI Di,ZHAI Jingshuo,WU Lili,ZHU Qinlei,XU Yanqing,HUANG Rudan.Synthesis, Structures and Properties of Two Complexes Based on Benzimidazole or Benzothiazole Ligand[J].Chemical Research in Chinese Universities,2014,30(2):185-189.

Chinese Journal of Polymer Science

2008年第2期

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SYNTHESIS AND PROPERTIES OF POLY(AROMATIC DIACETYLENE)S CONTAINING FLUORENE

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