摘要
As an endothermic hydrocarbon fuel,pentacyclo[6.3.1.02,7.03,5.09,11]dodecane has been synthesized from dicyclopentadiene catalyzed by Zn(Cu).Effects of catalyst ingredients,catalyst amount,temperature on yield of titled compound were investigated.The optimal conditions were: 15 ℃,n(DCPD)∶n(Zn(Cu))∶n(CH2I2)=1∶4∶8.Under the above conditions the conversion of dicyclopentadiene was 99.7% and the yield of pentacyclodocane reached 91.5%.
As an endothermic hydrocarbon fuel,pentacyclo[6.3.1.02,7.03,5.09,11]dodecane has been synthesized from dicyclopentadiene catalyzed by Zn(Cu).Effects of catalyst ingredients,catalyst amount,temperature on yield of titled compound were investigated.The optimal conditions were: 15 ℃,n(DCPD)∶n(Zn(Cu))∶n(CH2I2)=1∶4∶8.Under the above conditions the conversion of dicyclopentadiene was 99.7% and the yield of pentacyclodocane reached 91.5%.
出处
《燃料化学学报》
EI
CAS
CSCD
北大核心
2007年第5期637-640,共4页
Journal of Fuel Chemistry and Technology
