期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

新型绿色化学反应介质的研究进展 被引量：10

Progress on New Reaction Media in Green Chemistry
下载PDF
导出
摘要 综述了绿色化学在反应介质方面的研究进展。新型的有机合成反应介质主要包括离子液体、超临界流体、水溶剂及微波无溶剂技术。这些新型反应介质不仅可以取代传统的挥发性有毒有害有机溶剂,同时还可提高反应的活性和选择性,加速反应的进行,且有利于催化剂的回收利用及产品的分离。新型绿色化学反应介质是实现有机合成绿色化的重要途径。 Progress of green chemistry on new reaction media was reviewed. The new reaction media mainly include ionic liquids, supercritical liquids, water solvents and solvent-free microwave irradiation technology, which can not only substitute traditional toxic, harmful and volatile organic solvents, but also improve reaction activity and selectivity, with catalyst recycled and products easily separated. The new reaction medium is an important way for green synthesis.
作者 樊丽华 陈红萍 粱英华
机构地区 河北理工大学化学工程与生物技术学院
出处 《环境科学与技术》 CAS CSCD 北大核心 2007年第12期108-112,共5页 Environmental Science & Technology
关键词 绿色化学 有机合成 反应介质 离子液体 超临界流体 过热水 微波辐射 green chemistry organic synthesis reaction medium ionic liquid supercritical liquid overheated water solvent-free microwave irradiation
分类号 TQ02 [化学工程] X13 [环境科学与工程—环境科学]
  • 相关文献

参考文献51

  • 1[1]Gani R,Concepción J G,Constable D J C.Method for selection of solvents for promotion of organic reactions[J].Computers and Chemical Engineering,2005,29:1661-1676.
  • 2[2]Oiivier H,Magna L.Ionic liquids:perspectives for organic and catalytic reactions[J].Journal of Molecular Catalysis A:Chemical,2002,(182-183):419-437.
  • 3[3]Zhang X Y,Fan X S,Niu H Y,et al.An ionic liquid as a recyclable medium for the green preparation of α,α'-bis (substituted benzylidene) cycloalkanones catalyzed by FeCl3·6H2O[J].Green Chem,2003,5(2):267-269.
  • 4[4]Gui Jianzhou,Deng Youquan,Hu Zhide,et al.A novel task-specific ionic liquid for Beckmann rearrangement:a simple and effectve way for product separation[J].Tetrahedron Letters,2004,45:2681-2683.
  • 5[5]Zhang Qinghua,Shit Feng,Gu Yanlong,et al.Efficient and eco-friendly process for the synthesis of N-substituted 4-methylene-2-oxazolidinones in ionic liquids[J].Tetrahedron Letters,2005,46:5907-5911.
  • 6[6]Sun Jianmin,Fujita S,Arai M.Development in the green synthesis of cyclic carbonate from carbon dioxide using ionic liquids[J].Journal of Organometallic Chemistry,2005,690:3490-3497.
  • 7[7]Ranu B C,Dey S S.Catalysis by ionic liquid:a simple,green and efficient procedure for the Michael addition of thiols and thiophosphate to conjugated alkenes in ionic liquid,[pmim]Br[J].Tetrahedron,2004,60(19):4183-4188.
  • 8[8]Hagiwara H,Sayuri T,Okabe T,et al.Conjugate addition of unmodified aldehydes:recycle of heterogeneous amine catalyst and ionic liquid[J].Green Chem,2002,4(5):461-463.
  • 9[9]Doherty S,Goodrich P,Hardacre C,et al.Marked enantioselectivity enhancements for Diels-Alder reactions in ionic liquids catalysed by platnum diphosphine complexes[J].Green Chem,2004,6(3):63-67.
  • 10宛新华.DESIGN AND SYNTHESIS OF NOVEL CHIRAL IONIC LIQUIDS AND THEIR APPLICATION IN FREE RADICAL POLYMERIZATION OF METHYL METHACRYLATE[J].Chinese Journal of Polymer Science,2003,21(3):265-270. 被引量：5

二级参考文献135

  • 1高德禄,张和民.微波炉及其应用[J].现代科学仪器,1993(2):42-44. 被引量：4
  • 2林春绵,潘志彦.超临界氧化技术在有机废水处理中的应用[J].浙江化工,1996,27(2):16-20. 被引量：31
  • 3[1]B. Neises, W. Steglich, Angew. Chem. Int. Ed., 1978, 17, 522.
  • 4[2]P. Wasserscheid, W. Keim, Angew. Chem. Int. Ed., 2000, 39, 3772.
  • 5[3]R. Sheldon, Chem. Commun., 2001, 2399.
  • 6[4]Crystal data for 3b: C21H22FeO2 MW = 362.25, prism, space group P21/a, a = 11.6361 (13), b =10.8045 (10), c = 13.722 (2)A,β = 95.489 (5), V = 1004.9 (3) A3, Z = 4, Dc= 1.401 g / cm3, μ (MoKα=8.87 cm-1, F (000) = 760.00. Crystal size 0.22×0.21×0.19 mm3, 3925 independent reflections(Rint＝0.045), 13886 reflections collected. R = 0.043, wR = 0.086. Structure solution:direct methods (SHELX97); refinement method: full-matrix least-squares on F2.
  • 7Welton, T., Chem. Rev., 1999, 99: 2071.
  • 8Dupont, J., de Souza, R.F. and Suarez, P.A.Z., Chem. Rev., 2002, 102:3667.
  • 9Howarth, J., Hanlon, K., Fayne, D. and McCormac, P., Tetrahedron Lett, 1997, 38:3097.
  • 10Earle, M.J., McCormac, P.B. and Seddon, K.R., Green Chemistry, 1999, 1 : 23.

共引文献142

同被引文献109

引证文献10

二级引证文献26

环境科学与技术
2007年 第12期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部