几类按反Markovnikov规则方向进行的加成反应

In Most Reactions of Organic Chemistry Some Addition Succeed in the Opposite Direction of Markovnikov

在有机化学反应中 ,大多数不对称结构的烯烃与酸加成时按马氏规则方向进行 ,但也有一些反应如在过氧化物存在条件下的反应、硼氢化氧化反应和某些烯烃衍生物的加成反应等是按反马氏规则方向进行的 ,论文对此进行了归纳总结 .

In most reactions of organic chemistry,asymmetry olefin with acid addition succeed in the direction of Markovnikov,while some reactions do in the opposite direction such as post oxide,boron hydride oxidize and some olefin derivatives.These are summarized in this paper.