摘要
阐述了采用氨钙体系催化剂、以正己烷为溶剂的沉淀聚合制备聚氧化乙烯(PEO)的方法。研究了催化剂用量、反应温度、反应时间及溶剂含水量与PEO收率及其相对分子质量的关系。结果表明,PEO的收率随催化剂用量的增加而增加,其黏均相对分子质量(Mη)则随催化剂用量的增加而降低;反应温度对PEO的收率及其Mη的影响略小;反应时间的延长会使PEO的收率及其Mη增大;溶剂正己烷的含水量会显著降低PEO的收率及其Mη。当反应温度为25~40℃、反应时间为4~6h、催化剂用量为单体质量的1%~2%时,可得到Mη为(3~8)×105的PEO,聚合收率高于80%。
Poly(ethylene oxide) (PEO) was synthesized with calcium ammine as catalyst system and hexane as solvent,and the relationship among catalyst amounts,polymerization temperature,polymerization time and moisture of solvent with the yield of PEO and its relative molecular mass were investingated.The results showed that with the increase of catalyst amount,the yield of PEO increased,while the viscosity-average relative molecular mass (M-η) of it decreased.The polymerization temperature had a little effects on the...
出处
《石化技术与应用》
CAS
2008年第2期128-130,共3页
Petrochemical Technology & Application
关键词
聚氧化乙烯
氧化乙烯
开环聚合
相对分子质量
收率
poly(ethylene oxide)
ethylene epoxide
ring-opening polymerization
relative molecular mass
yield