期刊文献+

聚乙二醇接枝方法及其在膜表面化学改性中的应用 被引量:4

Grafting techniques of poly(ethylene glycol) and its application in membrane surface chemical modification
下载PDF
导出
摘要 聚乙二醇是一类亲水性长链聚合物.在膜材料表面接枝聚乙二醇,可以有效改善膜的亲水性,提高膜的耐污染性.介绍了聚乙二醇分子结构特征,重点叙述了包括化学法、紫外光照法、等离子体法以及臭氧化法等聚乙二醇在膜表面改性中的接枝方法.膜通过改性,接触角降低,蛋白质吸附显著减少,通量恢复率得到有效改善. Poly(ethylene glycol)(PEG) is a hydrophilic polymer which has flexible long chain.The immobilization of PEG on membrane surface is a potent technique to improve the hydrophilicity and anti-fouling ability of the membrane.The molecular characteristics of PEG and its grafting techniques such as chemical,UV photo-induced,plasma and ozone oxidation methods in membrane surface modification are introduced.By the immobilization of PEG,membrane water contact angles are reduced,which means their hydrophilicities are improved,meanwhile the adsorbed amounts of protein are decreased and the flux recoveries are improved.
出处 《膜科学与技术》 CAS CSCD 北大核心 2006年第6期81-87,共7页 Membrane Science and Technology
基金 国家973计划项目(2003CB615703)
关键词 抗污染膜 聚乙二醇 表面改性 接枝方法 anti-fouling membrane polyethylene glycol surface modification grafting techniques
  • 相关文献

参考文献17

  • 1Mulder M 李琳(译).膜技术基本原理[M].北京:清华大学出版社,1999.270-293.
  • 2[4]Freger V,Gilron J,Belfer S.TFC polyamide membranes modified by grafting of hydrophilic polymers:an FT-IR/AFM/TEM study[ J ].J Membr Sci,2002,209:283 -292.
  • 3[5]Peterson R J.Composite reverse osmosis and nanofiltration membranes[J].J Membr Sci,1993,83:81-150.
  • 4[6]Michael A S.Membrane,membrane process and their application:needs,unsolved problems and challenges in the1990's[ J ].Desalination,1990,77:5-34.
  • 5李娜,刘忠洲,续曙光.耐污染膜——聚乙烯醇膜的研究进展[J].膜科学与技术,1999,19(3):1-7. 被引量:41
  • 6[8]Thom V H,Altankov G,Groth T,et al.Optimizing cell-surface interactions by photografting of poly (ethylene glycol)[J ].Langmuir,2000,16:2756-2765.
  • 7[9]Kingshott P,Thissen H,Griesser H J.Effects of cloudpoint grafting,chain length,and density of PEG layers on competitive adsorption of ocular proteins[J].Biomaterials,2002,23:2043-2056.
  • 8[10]Kim Y H,Han D K,Park K D,et al.Enhanced blood compatibility of polymers grafted by sulfonated PEO via a negative cilia concept[J].Biomaterials,2003,24:2213-2223.
  • 9[11]Kim Y W,Ahn W S,Kim J J,et al.In situ fabrication of self-transformable and hydrophilic poly(ethylene glycol) derivative-modified polysulfone membranes[ J ].Biomaterials,2005,26:2867-2875.
  • 10[13]Bergstrom K,Holmberg K.Reduction of fibrinogen adsorption on PEG-coated polystyrene surfaces[ J ].JBiomed Mater Res,1992,26:779-790.

二级参考文献18

  • 1吴秋林,吴照和.PVA—PE复合亲水分相膜的研制[J].膜科学与技术,1995,15(4):29-32. 被引量:13
  • 2刘忠洲.膜分离技术在环境中的应用.膜分离技术在环境中应用研讨会论文集[M].井冈山,1997..
  • 3严瑞暄 陈振兴 等.水溶性聚合物[M].北京:化学工业出版社,1988.25-74.
  • 4高以xuan 叶凌碧.膜分离技术基础[M].北京:科学出版社,1987.108-109.
  • 5刘忠洲,膜分离技术在环境中应用研讨会论文集,1997年
  • 6Wang Qi,J Appl Polym Sci,1997年,64卷,2089页
  • 7Elimelech M,J Membr Sci,1997年,127卷,101页
  • 8Lang K,Desalination,1996年,104卷,185页
  • 9Li R H,J Membr Sci,1996年,111卷,115页
  • 10Lang K,Canadian J Chem Eng,1995年,73卷,681页

共引文献44

同被引文献41

  • 1詹劲,张敏莲,刘铮.膜材料与生物分子相互作用的分子模拟[J].化工学报,2005,56(11):2157-2161. 被引量:3
  • 2Ren Zhiyong,Ma Dezhu,Yang Xiaozhen.H-bond andconformations of donors and acceptors in model polyetherbased polyurethanes[J].Polymer,2003,44(20):6419-6425.
  • 3Cameron R Kinnane,Kim Wark,Georgina K Such,Angus P R Johnston,Frank Caruso.Peptide-functionalized,low-biofouling click multilayers for promoting cell adhesionand growth[J].Small,2009,5(4):444-448.
  • 4Ayse Asatekin,Seoktae Kang,Menachem Elimelech,Anne M Mayes.Anti-fouling ultrafiltration membranescontaining polyacrylonitrile-graft-poly(ethylene oxide)comb copolymer additives[J].Journal of MembraneScience,2007,298(1/2):136-146.
  • 5Jagdeesh Bandekar,Yuzi Okuzumi.FT-IR spectroscopicstudies of polyurethanes(Ⅲ):Quantum chemical studiesof the carbamate group and the urethane C—O—C hydrogenbonding in polyurethanes[J].Journal of MolecularStructure:THEOCHEM,1993,281(2/3):113-122.
  • 6Gilron J,Belfer S,Vaisanen P,Nystrom M.Effects ofsurface modification on antifouling and performanceproperties of reverse osmosis membranes[J].Desalination,2001,140(2):167-179.
  • 7Li Qilin,Xu Zhihua,Pinnau Ingo.Fouling of reverseosmosis membranes by biopolymers in wastewater secondaryeffluent:role of membrane surface properties and initialpermeate flux[J].Journal of Membrane Science,2007,290(1/2):173-181 .
  • 8Ochoa N A,Masuelli M,Marchese J.Development ofcharged ion exchange resin-polymer ultrafiltration membranes toreduce organic fouling[J].Journal of Membrane Science,2006,278(1/2):457-463.
  • 9Heru Susanto,Mathias Ulbricht.Influence of ultrafiltrationmembrane characteristics on adsorptive fouling withdextrans[J].Journal of Membrane Science,2005,266(1/2):132-142.
  • 10S. Zanini,M. Müller,C. Riccardi,M. Orlandi.Polyethylene Glycol Grafting on Polypropylene Membranes for Anti-fouling Properties[J].Plasma Chemistry and Plasma Processing.2007(4)

引证文献4

二级引证文献3

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部