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卤素对于燃烧中CO氧化和NO生成的影响 被引量：2

INFLUENCE OF HALOGEN ON CO OXIDATION AND NO FORMATION IN COMBUSTION
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摘要 卤族元素在燃烧时会影响CO的氧化和NO的生成。本文通过化学平衡方法分析了H2O和HCl对于CO氧化的协同效应,在非均匀布风流化床中进行了PVC塑料与煤或半焦的混烧试验,测量了CO和CH4的排放特性,从而从理论上和实验上证明了HCl对CO氧化的抑制作用。并给出了今后研究的方向和问题。 The effects of halogens on the oxidation of carbon monoxide (CO) and nitrogen oxide (NO) emissions are discussed by summarizing the previous researches. The synergies of H2O and HCl on the oxidation of CO are analyzed by the method of chemical equilibrium. The co-combustion of PVC plastic and coal or char is studied in an ICFB. And the emissions of CO and CH4 are measured. The computational study and experimental investigation both show HCl can inhibit the oxidation of CO. The problems needed to be studied in the future are also presented.
作者 张静伟 魏小林 盛宏至 张宇
机构地区 中国科学院力学研究所 中国科学院研究生院
出处 《工程热物理学报》 EI CAS CSCD 北大核心 2005年第z1期261-264,共4页 Journal of Engineering Thermophysics
基金 国家自然科学基金资助项目(No.50376068)
关键词 卤素 燃烧 CO氧化 NO生成 Halogen combustion CO oxidation NO formation
分类号 TK16 [动力工程及工程热物理—热能工程]
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参考文献14

  • 1[1]Vassilev S V, Eskenazy G M, Vassileva C G. Contents & Modes of Occurrence and Origin of Chlorine and Bromine in Coal. Fuel, 2000, 79(8): 903-921
  • 2[2]Bjorkman E, Stromberg B. Release of Chlorine from Biomass at Pyrolysis and Gasification Conditions. Energy and Fuels, 1997, 11(5): 1026-1032
  • 3[3]陈鹏.中国煤炭性质、分类和利用.北京:化学工业出版社,2002.279-281
  • 4[4]Roesler J F, Yetter R A, Dryer F L. Kinetic Interactions of CO, NOx, and HCl Emissions in Postcombustion Gases.Combustion and Flame, 1995, 100(3): 495-504
  • 5[5]Roesler J F, Yetter R A, Dryer F L. Inhibition and Oxidation Characteristics of Chloromethanes in Reacting CO/H2O/O2 mixtures. Combustion Science and Technology, 1996, 115(1-3): 69-82
  • 6[6]Linak W P, Wendt J O L. Nitrogen Oxide/Chlorine Interactions in a Laboratory Swirl Flame Combustor. Combustion Sciences and Technology, 1996, 115(1-3): 69-82
  • 7[7]Gokulakrishnan P, Lawrence A D. An Experimental Study of the Inhibiting Effect of Chlorine in a Fluidized Bed Combustor. Combustion and Flame, 1999, 116(4):640-652
  • 8[8]Lu D Y, Anthony E, Talbot R, et al. Understanding of Halogen Impacts in Fluidized Bed Combustion. Energy and Fuels, 2001, 15(3): 533-540.
  • 9[9]Winter F, Wartha C, Hofbauer H. The Relative Importance of Radicals on the N2O and NO Formation and Destruction Paths in a Quartz CFBC. In: Proceedings of the 14th International Conference on Fluidized Bed Combustion. Vancouver, Canada, 1997. 2:1131-1137
  • 10[10]Wei X-L, Schnell U, Han X-H, et al. Interactions of CO,HCl, and SOx in Pulverised Coal Flames. Fuel, 2004,83(9): 1227-1233

同被引文献20

  • 1李诗媛,别如山,王珩.流化床中焚烧处理含氯有机废液HCl排放及脱除研究[J].中国电机工程学报,2006,26(1):40-44. 被引量：10
  • 2Santoleri J J. Chlorinated hydrocarbon waste disposal and recovery systems[J]. Chemical Engineering Progress, 1973, 69(1): 68-74.
  • 3Gupta A K. Combustion of chlorinated hydrocarbons[J]. Chemical Engineering Communications, 1986, 41(1-6): 1-21.
  • 4Oppelt E T. Incineration of hazardous waste: a critical review [J]. Journal of the Air Pollution Control Association, 1987, 37(5): 556-586.
  • 5Saxena S S C, Jotshi C K. Management and combustion of hazardous wastes[J]. Progress in Energy and Combustion , 1996, 22(5): 401-425.
  • 6Chang D P Y, Sorbo N W, Law C K, et al. Relationships between laboratory and pilot-scale combustion of some chlorinated hydrocarbons[J]. Environmental Progress, 1989, 8(3):152-162.
  • 7Law C K. Consideration of droplet processes in liquid hazardous waste incineration[J]. Combustion Science and Technology, 1990, 74(1-6): 1-15.
  • 8Sorbo N W, Chang D P Y. Observations of chlorinated hydrocarbon droplet gasification[J]. Combustion Science and Technology, 1992, 85(1-6): 419-435.
  • 9Stry W J, Felske J D, Ashgriz N. Droplet combustion of chlorinated benzenes, alkanes and their mixtures in a dry atmosphere [J]. Environmental EngineeringScience, 2003, 20(2): 125-133.
  • 10Bose D, Senkan S M. On the combustion of chlorinated hydrocarbons [J]. Combustion Science and Technology, 1983, 35(1-4):187-202.

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工程热物理学报
2005年 第z1期

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