期刊文献+

(La_xSr_(1-x))(Ga_yMg_(1-y))O_3固体电解质的制备及性能研究 被引量:1

Preparation and Characterization of (La_xSr_(1-x))(Ga_yMg_(1-y))O_3 Solid Electrolyte
下载PDF
导出
摘要 采用固相法制备了锶,镁掺杂的镓酸镧(LSGM)固体电解质材料,并对其结晶结构、表面形貌和室温下的电导率进行了研究.XRD分析表明,LSGM样品具有正交钙钛矿结构.利用SEM,分析了烧结保温时间对LSGM样品表面形貌的影响.通过交流阻抗仪测试了室温下LSGM各个组分的电导率,发现在实验中所制备的组分范围内,LSGM体系具有以下特点固定Sr的掺杂量,电导率随Mg的增加而降低;固定Mg的掺杂量,电导率随Sr的增加而增加. Strontium and magnesium double doped LaGaO_3 (LSGM) solid electrolytes were prepared by means of solid state process. The phase structure, microstructure and ionic conductivity of these materials were measured. The XRD analysis shows that the LSGM samples possess orthorhombic perovskite structure. The different microstuctures of LSGM samples were affected by sintering time.The conductivity properties of LSGM samples are calculated by impedance data. It was found that LSGM samples possess the properties that...
出处 《四川大学学报(自然科学版)》 CAS CSCD 北大核心 2005年第S1期282-285,共4页 Journal of Sichuan University(Natural Science Edition)
基金 国家自然科学基金(60471044)
关键词 镓酸镧 电解质 固体氧化物燃料电池 LaGaO_3 electrolyte solid oxide fuel cell
  • 相关文献

参考文献3

二级参考文献35

  • 1孙家枢,郑启光,陶星芝,韦建辉,王涛.激光熔凝过共析ZrO_2-MgO快离子导体[J].科学通报,1995,40(10):954-955. 被引量:3
  • 2辜建辉,郑启光,陶星之,王涛,孙家枢.大功率CO_2激光熔凝稳定ZrO_2[J].无机材料学报,1995,10(1):76-80. 被引量:4
  • 3郭公毅.燃料电池[M].北京:能源出版社,1980.42-76.
  • 4[1]MINH N Q. Ceramic fuel cells [J]. J Am Ceram Soc, 1993, 76: 563-588.
  • 5[2]CASANOVA A. A consortium approach to commercialized westinghouse solid oxide fuel cell technology [J]. J Power Sources, 1998, 71: 65-70.
  • 6[3]ISHIHARA T, MATSUDA H, TAKITA Y. Doped LaGaO3 perovskite type oxide as a new oxide ionic conductor [J]. J Am Chem Soc, 1994, 116: 3 801-3 803.
  • 7[4]FENG M, GOODENOUGH J B. A superior oxide-ion conduc-tor [J]. Eur J Solid State Inorg Chem, 1994, t31: 663-672.
  • 8[5]LYBBYE D, POULSEN F W, MOGENSEN M. Conductivity of A-and B-site doped LaAlO3, LaGaO3, LaScO3 and LaInO3 perovskite [J]. Solid State Ionics, 2000, 128: 91-103.
  • 9[6]YAMAJI K, NEGISHI H, HORITA T, et al. Vaporization process of Ga from doped La*GaO3 electrolytes in reducing atmospheres [J], Solid State Ionics, 2000, 135: 389-396.
  • 10[7]AHMAD K A, TIETZ F, ST*;VER D. Material properties of La0.8Sr0.2Ga0.9+xO3-δ as a function of Ga content [J]. Solid State Ionics, 2000, 135: 543-547.

共引文献17

同被引文献17

  • 1汪灿,刘宁,石敏,许育东,张宏.Sr、Mg掺杂量对LaGaO_3基电解质离子电导率的影响[J].合肥工业大学学报(自然科学版),2004,27(10):1176-1180. 被引量:3
  • 2张乃庆,孙克宁,吴宁宁,周德瑞.中温SOFCLa_(0.9)Sr_(0.1)Ga_(0.8)Mg_(0.2)O_(3-δ)固体电解质的电性能研究[J].人工晶体学报,2004,33(3):354-357. 被引量:4
  • 3刘荣辉,马文会,王华,杨斌,戴永年.La_(0.9)Sr_(0.1)Ga_(0.8)Mg_(0.2)O_(3-δ)电解质材料的合成及性能研究[J].有色金属(冶炼部分),2006(4):36-39. 被引量:1
  • 4刘荣辉,马文会,王华,杨斌,戴永年.中温固体氧化物燃料电池新体系材料研制[J].电源技术,2007,31(2):109-112. 被引量:1
  • 5Hibino T, Hashimote A, Lnoue J. A low - operating - temperature solid oxide fuel cell in hydrocarbon - air mixture [ J ]. Science,2000,288 : 2031-2033.
  • 6Hibino T, Wang S Q, Kakimoto S, et al. One - chamber solid oxide fuel cell constructed from a YSZ electrolyte with a Ni anode and LSGM cathode [ J ]. Solid State Ionics ,2000,127:89-98.
  • 7Ishihara T, Matsuda H ,Takita Y. Effects of rare earth cations doped for La site on the oxide ionic concuctivity of LaGaO3 - based perovskite type oxide [ J ]. Solid State Ionics, 1995,79 : 147-151.
  • 8Will J, Mitterdorfer A, Kleinlogel C, et al. Fabrication of thin electrolytes for second - generation solid oxide fuel cells [ J ]. Solid State Ionics ,2000,31:79-96.
  • 9Gorelov V P, Bronin D I. The effect of doping and processing conditions on properties of La1-x SrxGa1-y MgyO3-α [J]. J of the European Ceramic Society,2001, 21:2311-2317.
  • 10Pradyot Datta, Peter Majewski. Synthesis and microstructural characterization of Sr- and Mg-substituted LaGaO3 solid electrolyte [ J ]. Materials Chemistry Physics,2007, 102 : 240-244.

引证文献1

二级引证文献7

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部