A Facile Preparation of New Chiral Diamines/Amino-acids (Alcohols) Derived from L-Proline

A Facile Preparation of New Chiral Diamines/Amino-acids (Alcohols) Derived from L-Proline

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摘要　　Living systems use enzymes to catalyze stereoselective reactions with very high fidelity. Since proline was demonstrated as the simplest "enzyme" that mimics type Ⅰ aldolase to catalyze aldol reaction,[1～3] it has attracted much attention in chemistry and other relative fields to design and synthesize highly efficient chemzyme or organocatalysts that can activate normally unreactive substances to useful asymmetric catalytic transformations.……

作者 FU,Yu-Qin TAO,Jing-Chao DING,Li-Na LIU,Wei-Min

机构地区 Department of Chemistry

出处《有机化学》 SCIE CAS CSCD 北大核心 2004年第z1期352-,共1页 Chinese Journal of Organic Chemistry

基金国家自然科学基金(No.20372059)和河南省自然科学基金(No.311020500)资助项目.

分类号 O62 [理学—有机化学]

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1[1]List, B.; Lerner, R. A.; Barbas Ⅲ, C. F. J. Am. Chem. Soc. 2000, 122, 2395.
2[2]Movassaghi, M.; Jacobsen, E. N. Science 2002, 298, 1904.
3[3]List, B. Tetrahedron 2002, 58, 5573.
4[4]Dalko, P. I.; Moisan, L. Angew. Chem., Int. Ed. 2001, 40, 3726.

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A Facile Preparation of New Chiral Diamines/Amino-acids (Alcohols) Derived from L-Proline

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