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Green Synthesis and Regioselective Control of Sn/I2 Mediated Allylation of Carbonyl Compounds with Crotyl Halide in Water

Green Synthesis and Regioselective Control of Sn/I2 Mediated Allylation of Carbonyl Compounds with Crotyl Halide in Water
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摘要   Barbier-type carbonyl allylation is particularly useful due to ease of operation and the availability and tractability of allylic substrates,[1] Metals such as indium, zinc and tin are often used as the mediator. Here we present a green approach toward the synthesis, that is, Sn/I2 mediated allylation of carbonyl compounds with crotyl halide in water.……
出处 《有机化学》 SCIE CAS CSCD 北大核心 2004年第z1期364-,共1页 Chinese Journal of Organic Chemistry
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  • 1[1]For reviews and examples, see:(a) Li, C. J.; Chan, T. H. Organic Reactions In Aqueous Media, John Wiley & Sons, New York, 1997.(b) Li, C. J.; Chan, T. H. Tetrahedron 1999, 55, 11149.(c) Li, C. J.; Chan, T. H. Tetrahedron Lett. 1991, 32, 7017.(d) Yamamoto, Y.; Asano, N. Chem. Rev. 1993, 93, 2207.

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