Preparation and Reactions of Amino Acid Ester Sulfones as New Remote Asymmetrical Induced Reagents

Preparation and Reactions of Amino Acid Ester Sulfones as New Remote Asymmetrical Induced Reagents

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摘要　　The development of chiral auxiliary-controlled asymmetric synthesis has been receiving increasing interest in recent yearsfi,2] Various chiral auxiliary reagents have been observed[3] and a lot of results showed that variation of the chiral auxiliary could influence asymmetric induction. Recently, it has been reported the reaction of the aminated sulfones as a remote chiral auxiliary with α,β-unsaturated carbonyl compounds.[4] Here we would like to report the preparation of amino acid ester sulfones as new remote asymmetrical induced reagents and their reactions with α,β-unsaturated esters.……

作者 ZHOU,Cheng-He BAI,Xue LI,Tan-Qing WU,Jun Alfred Hassner

机构地区 College of Chemistry and Chemical Engineering School of Pharmaceutical Sciences

出处《有机化学》 SCIE CAS CSCD 北大核心 2004年第z1期379-,共1页 Chinese Journal of Organic Chemistry

基金 Project supported by the Sciences and Technology Committee of Chongqing, the Personnel Department of China, the National Natural Science Foundation of China, and the Fred and Barbara Kort Sino-Israel Postdoctoral Fellowship Program.

分类号 O62 [理学—有机化学]

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1[1]Roos, G. Compendium of Chiral Auxiliary Applications, Vol. 3, Academic Press, San Diego, 2002, pp. 952～ 1120.
2[2]Seyden-Penne, J. Chiral Auxiliaries and Ligands in Asymmetric Synthesis, John Wiley & Sons, Inc., New York, 1995.
3[3]Perlmutter, P. Advanced Asymmetric Synthesis, Ed.: Stephenson, G. R., Champman & Hall, London, 1996, pp. 222～229.
4[4]Ghera, E.; Kleiman, V.; Hassner, A. J. Org. Chem. 1999, 64, 8.

1Yan Tao CHEN,Wen Ting HUA,Qi Yi XING(Department of Chemistry Peking University Beijing 100871).Synthesis of Macrocycles Containing Amino Acid Ester and Aryl-heterocyclic Units[J].Chinese Chemical Letters,1997,8(12):0-0.
2Su Yun Liu,Shigeo Katsumura.An improved synthesis of (-)-7-isopropyl-cis-l-amino-2-indanol the chiral auxiliary for 6π-azaelectrocyclization[J].Chinese Chemical Letters,2009,20(10):1204-1206.
3Peng DIAO,Dian Lu JIANG,Xiao Li CUI,Deng Ping GU,Ru Ting TONG,Bing ZHONG(Department of Chemistry. Hebei Teacher’s University. Shijiazhuang 050016)(Institute of Coal Chemistry. Chinese Academy of Sciences. Taiyuan 030001).Asymmetrical Conductivity of TCNQ Modificd Au/Thiol-Lipid Bilayers in Fe(CN)_6^(3-/4-)solution[J].Chinese Chemical Letters,1999,10(7):587-590.
4Jian Xue,Lu Ling Wu,Xian Huang.The facile insertion of β-keto sulfones to arynes:The direct preparation of polysubstituted ortho-keto benzyl sulfones[J].Chinese Chemical Letters,2008,19(6):631-633.
5Xiao Bing WANG,Dai Hua TANG,Jian Cheng ZHANG,Xin Hou LIU(Institute of Photographic Chemislry. Chinese Academy of Sciences. Beijing 100101).Synthesis of Novel Asymmetrical Tri-tert-butyl Naphthalocyanine Using Structurally Distorted Subnaphthalocyanine[J].Chinese Chemical Letters,1999,10(5):353-356.
6Peng Zhou,Juanjuan Jin,Bingguang Zhang,Changjun Yang,Zehui Zhang,Zhe Li,Kejian Deng.Synthesis of Asymmetrical Monobenzo-Substituted Cobalt Thioporphyrazines and Their Biomimetic Catalytic Property[J].Chinese Journal of Chemistry,2016,34(10):1013-1020.
7Xiu Fang LIU,Ying Xin XIAO,Guo Jun ZHANG,Han Sheng XU,Fan Bo ZHENG.STUDIES ON THE SYNTHESIS AND ANTITUMOR ACTIVITY OF AMINO ACID ESTER DERIVATIVES OF BENZISOSELENAZOLONE[J].Chinese Chemical Letters,1992,3(3):161-162.
8Pei Qiang HUANG,Xiang Su,FEI and Hong ZHENG(Department of Chemistry, Xiamen University, Xiamen 361005).α-AMIDOALKYLATION　VIA　SULFONES:TOWARDS　THE　SYNTHESIS　OF　ANT　VENOM　ALKALOIDS[J].Chinese Chemical Letters,1995,6(9):739-742.
9Cai Ding XU Ji Qing JIANG Xian HUANG Department of Chemistry,Hangzhou University,Hangzhou 310028..A NEW SYNTHESIS OF SULFONES VIA THE ZINC—ASSISTED COUPLING OF ARENESULFONYL CHLORIDE WITH ALKYL HALIDES[J].Chinese Chemical Letters,1993,4(12):1051-1052.
10郑云法,包伟良,张永敏.Addition of Organosamarium Reagents to α,β-Unsaturated Esters and Nitroalkenes[J].厦门大学学报（自然科学版）,1999,38(S1):327-327.

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Preparation and Reactions of Amino Acid Ester Sulfones as New Remote Asymmetrical Induced Reagents

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