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Spontaneous Polymerization of An Amino Acid Based Amphiphile at Air/water Interface Investigated by ESI-MS and Transmission IR Spectrometry

Spontaneous Polymerization of An Amino Acid Based Amphiphile at Air/water Interface Investigated by ESI-MS and Transmission IR Spectrometry
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摘要   Self-assemblies of amphiphilic molecules are proposed to play a ubiquitous role at the early stages of evolution in the formation of primitive biopolymers. [1] As regard to the significance of N-phosphoryl amino acids as a model for the co-evolution of protein and nucleic acids at the prebiotic stage, [2] amphiphilic N-phosphoryl amino acids with two hydrophobic tails were synthesized. [3]……
出处 《有机化学》 SCIE CAS CSCD 北大核心 2003年第z1期197-197,共1页 Chinese Journal of Organic Chemistry
基金 Project supported by the National Natural Science Foundation of China (No. 20272032) and the Teaching and Research Award Program for Out standing Young Teachers in Higher Education Institutions of Ministry of Education.
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  • 1[1]Zepik, H.; Shavit, E.; Tang, M.; Jensen, T. R.; Kjaer, K.; Bolbach, G.; Leiserowitz, L.; Weissbuch, I.; Lahav, M.Science 2002, 295, 1266.
  • 2[2]Zhao, Y.-F.; Cao, P.-S. J. Biol. Phys. 1994, 20, 283.
  • 3[3]Deng, C.-H.; Li, Y.-M.; Xu, N.; Zhao, Y.-F. J. Chem. Res., Synop. 1999, 10, 589.

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