Asymmetric Michael Reaction of Malononitrile Catalyzed by Chiral Ru(Ⅱ) Complex and Achiral Base

Asymmetric Michael Reaction of Malononitrile Catalyzed by Chiral Ru(Ⅱ) Complex and Achiral Base

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摘要　　Michael addition reactions represent one of the most important carbon-carbon bond forming reactions in modern synthetic organic chemistry. [1 ～3] We achieved catalytic enantioselective Michael addition reactions of malononitrile with chiral vicinal diamine-Ru(Ⅱ) complex in the presence of achiral base. High yields and moderate ee were observed.……

作者 MA Ya-Ping XING Zhi-Kui ZHU Jin CUI Xin CUN Lin-Feng DENG Jin-Gen

机构地区 Key Laboratory of Asymmetric Synthesis and Chirotechnology of Sichuan Province and Union Laboratory of Asymmetric Synthesis

出处《有机化学》 SCIE CAS CSCD 北大核心 2003年第z1期61-61,共1页 Chinese Journal of Organic Chemistry

分类号 O62 [理学—有机化学]

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1[1]Murahashi, S.-I. et al. J. Am. Chem. Soc. 1995, 117, 12436.
2[2]Ito, Y. et al. J. Am. Chem. Soc. 1992, 114, 8295.
3[3]Krause, N. et al. Synthesis 2001, 171.

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Asymmetric Michael Reaction of Malononitrile Catalyzed by Chiral Ru(Ⅱ) Complex and Achiral Base

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