摘要
乙酰丙酮、邻苯二胺与高氯酸以1∶1∶1的摩尔比在苯溶剂中反应,合成了标题化合物。通过红外以及X-衍射分析,确认了其化学结构。标题化合物的分子式为:C22H26N4C l2O8,Mr=545.37,晶体属单斜晶系,P2(1)c空间群,晶胞参数:a=7.4184(9),b=18.434(2),c=18.535(2),β=95.892(2)°,V=2521.2(5)3,Z=4,Dc=1.437Mg/m3,R1=0.0839,wR2=0.2488[I>2σ(I)]。
Acetylacetone,o-phenylenediamine and perchloric acid in the molar ratio of 1:1:1 in benzene reaction,a new synthetic compounds acetylacetone with o-phenylenediamine Schiff base single perchlorate.By infrared and X-ray crystallography Determination,the title compound confirmed the chemical structure and crystal structure.The title compound for the chemical formula : C22H26N4Cl2O8,Mr =545.37,the crystals are triclinic,space group P2(1)c,unit cell parameters: a=7.4184(9),b=18.434(2),c=18.535(2),β=95.892(2) ...
出处
《洛阳师范学院学报》
2008年第5期68-70,共3页
Journal of Luoyang Normal University
关键词
乙酰丙酮
邻苯二胺
高氯酸
SCHIFF碱
晶体结构
Acetylacetone
o-phenylenediamine
perchloric acid
Schiff base single
crystal structure
