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溶剂稳定的钯纳米颗粒自组装体的控制合成 被引量：2

Synthesis of Solvent-Stabilized Self-Assemblies of Pd Nanoparticles
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摘要 以甲基异丁酮为溶剂,在少量乙二醇和KOH存在下,乙酸钯经微波辐照加热60 s可以得到溶剂稳定的海胆状Pd纳米颗粒自组装体,颗粒平均粒径较小,大小均匀,分散性好.产物用透射电子显微镜(TEM)、X-射线光电子能谱(XPS)和X-射线粉末衍射(XRD)进行了表征. Solvent-stabilized urchin-like self-assemblies of Pd nanoparticles with a small average diameter,uniform size and well dispersed were obtained by thermal decomposition of palladium acetate with methyl isobutyl ketone as a solvent in the presence of a small amount of ethylene glycol and KOH under microwave irradiation for 60 sec.The as-prepared Pd nanoparticle self-assemblies were characterized by transmission electron microscopy,X-ray powder diffraction and X-ray photoelectron spectroscopy.
作者 童霞 王飞 于明 刁香菊 黄涛 刘汉范
机构地区 中南民族大学化学与材料科学学院催化材料科学湖北省暨国家民委-教育部共建重点实验室
出处 《中南民族大学学报（自然科学版）》 CAS 2009年第1期4-7,共4页 Journal of South-Central University for Nationalities：Natural Science Edition
基金 国家自然科学基金资助项目(20673146) 湖北省自然科学基金资助项目(2006ABA366) 中南民族大学科学基金资助项目(YZZ05002)
关键词 乙酸钯 钯纳米颗粒 自组装体 微波 palladium acetate palladium nanoparticles self-assembly microwave
分类号 TB381 [一般工业技术—材料科学与工程]
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参考文献10

  • 1Narayanan R,,El-Sayed M A.Changing catalyticactivity during colloidal platinum nanocatalysis dueto shape changes:electron-transfer reaction[].Journal of the American Chemical Society.2004
  • 2Burda C,Chen X,Narayanan R,et al.Chemistry andproperties of nanocrystals of different shapes[].Chemical Reviews.2005
  • 3Helmut B,Richards R M.Nanoscopic metal particles-Syn-thetic methods and potential applications[].Eur J InorgChem.2001
  • 4Sun Y G,Tao Z L,Chen J,et al.Ag Nanowires Coated with Ag/Pd Alloy Sheaths and Their Use as Substrates for Reversible Absorption and Desorption of Hydrogen[].Journal of the American Chemical Society.2004
  • 5H. P. Choo,K. Y. Liew,W. A. K. Mahmood,H. Liu.Morphology and crystalline structure of polymer stabilized Pd nanoparticles[].Journal of Materials Chemistry.2001
  • 6Y. J. Xiong,J. Y. Chen,B. Wiley,and Y. N. Xia.Understanding the role of oxidative etching in the polyol synthesis of Pd nanoparticles with uniform shape and size[].Journal of the American Chemical Society.2005
  • 7Xiong,Y.J,Xia,Y.N.Shape-Controlled Synthesis of Metal Nanostructures:The Case of Palladium[].Advanced Materials.2007
  • 8Y. Xiong,J. M. McLellan,Y. Yin,Y. Xia.Synthesis of Palladium icosahedra with twinned structure by blocking oxidative etching with citric acid or citrate ions[].Angewandte Chemie International Edition.2007
  • 9Tano T,Esumi K,Meguro K.Preparation of organo palladium particles from thermal decomposition of its organic complex in organic solvents[].Langmuir.1989
  • 10Yixian CHEN, Baolin HE and Hanfan LIU Hubei Key Laboratory for Catalysis and Material Science, University of South-Central for Nationalities, Wuhan 430074, China PCLCC, State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China.Preparation and Characterization of Palladium Colloidal Nanoparticles by Thermal Decomposition of Palladium Acetate with Microwave Irradiation[J].Journal of Materials Science & Technology,2005,21(2):187-190. 被引量：4

二级参考文献24

  • 1G.Schmid: Clusters and Colloids: From Theory to Application, New York, 1994.
  • 2J.H.Fendler: Nanoparticles and Nanostructured Films,Weinheim, 1998.
  • 3A.P.Alivisatos: Sci., 1996, 271, 933.
  • 4A.Roucoux, J.Schulz and H.Patin: Chem, R.ev., 2002,102, 3757.
  • 5N.Toshima, Y.Shiraishi, T.Teranishi, M.Miyake,T,Tominaga, H,Watanabe, W.Brijoux, H.Bonnemann,and G.Sckmid: Appl Organomet. Chem., 2001, 15, 178.
  • 6C.N.R.Rao, G.U.Kulkarni, P.J.Thomas and P.P.Edwards: Chem. Soc. Rev., 2000, 29, 27.
  • 7J.D.Aiken, Ⅲ and R G Finke: J. Mol Carat. A: Chem.,1999, 145, 1.
  • 8K.Esumi, T.Tano and K.Meguro: Langmuir, 1989, 5, 268.
  • 9T.Tano K.Esumi and K.Meguro: J. Colloid Interface Sci.1989, 133, 530.
  • 10R.A.Abramovitch: Org. Prep. Proc. Int., 1991, 23, 683.

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中南民族大学学报（自然科学版）
2009年 第1期

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