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STRUCTURE EVOLUTION OF THE CYLINDRICAL PHASE OF DIBLOCK COPOLYMERS IN FILMS

STRUCTURE EVOLUTION OF THE CYLINDRICAL PHASE OF DIBLOCK COPOLYMERS IN FILMS
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摘要 In the weak segregation limit,the structure evolution of the hexagonal cylindrical phase of diblock copolymers in films was investigated.Employing the Landau-Brazovskii mean field theory,we obtained three amplitude parameters as functions of temperature,surface field strength and film thickness.By controlling confinement size and surface field strength, lamellae and undulated lamellae appear in the cylindrical bulk phase of diblock copolymers.'Phase diagrams'of confinement-induced structures are constructed... In the weak segregation limit,the structure evolution of the hexagonal cylindrical phase of diblock copolymers in films was investigated.Employing the Landau-Brazovskii mean field theory,we obtained three amplitude parameters as functions of temperature,surface field strength and film thickness.By controlling confinement size and surface field strength, lamellae and undulated lamellae appear in the cylindrical bulk phase of diblock copolymers.'Phase diagrams'of confinement-induced structures are constructed...
作者 谭红革
机构地区 College of Science
出处 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2008年第6期759-766,共8页 高分子科学(英文版)
基金 supported by the National Natural Science Foundation of China (No.20504027) Scientific Research Foundation of Civil Aviation University of China (No.05qd05s).
关键词 THEORY Block copolymers FILM SURFACES Mean field. Theory Block copolymers Film Surfaces Mean field.
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