1,4,6,6-四硝基-1,4-二氮杂环庚烷的制备及性质

The Preparation and Properties of 1,4,6,6-Tetranitro 1,4-diazacycloheptane

:2 ,2 -二硝基 - 1,3-丙二醇与乙二胺进行曼尼希缩合反应 ,生成 3,3,7,7-四硝基 - 1,5 -二氮杂双环 [3.3.2 ]癸烷 ( ) ,该中间体 用硝酸 -五氧化二磷混合物硝化 ,得到 1,4,6 ,6 -四硝基 - 1,4-二氮杂环庚烷 ( )。对 的物理性质、热稳定性及爆炸性质进行了初步的研究。

Reaction of 2，2-dinitropropanediol with ethylene diamine by Mannich condensation formed 3,3,7,7-tetranitro-1,5-diazabicyclo［3.3.2］decane(Ⅰ), which was subjected to nitration to yield the title compound, 1，4，6，6-tetranitro-1，4-diazacycloheptane (Ⅱ). Preliminary investigation was made on physical, thermal and explosive properties of Ⅱ.