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新型热塑性聚氨酯弹性体微相分离的定量研究 被引量:8

Quantitative Estimate of Phase Segregation of a New Type of Thermoplastic Polyurethane Elastomer
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摘要 基于端羟环氧乙烷 -四氢呋喃无规共聚醚、异佛尔酮二异氰酸酯以及 1,4-丁二醇 ,采用熔融二步法合成了一系列新型的用于固体推进剂的热塑性聚氨酯弹性体。以 DSC及 FTIR为主要测试手段 ,建立了影响热塑性弹性体性能的微相分离程度的定量方程 ,并以此对所合成的 A new type thermoplastic polyurethane elastomer for using as binder in solid propellent were prepared with melt-prepolymerization method based on ethylene oxide-tetrahydrofuran random copolyehter,isophorone diisocyanate and 1,4-butanediol.Quantitative estimate of phase segregation were discussed with quantitative equation established based on DSC and FTIR results.
出处 《火炸药学报》 CAS CSCD 2000年第4期58-60,共3页 Chinese Journal of Explosives & Propellants
关键词 热塑性弹性体 聚氨酯 微相分离 Thermoplastic elastomer Polyurethane Phase segregation
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参考文献5

  • 1[2] 多英全.火药用热塑性聚氨酯弹性体的合成及应用研究[D].北京:北京理工大学,1998.
  • 2[3] T R Hesketh,S L Cooper. DSC analysis of morphologycal change in segmented elastomers [J].Polymer Engineering and Sci,1980,20(3):190~197.
  • 3[4] Y Camberlin,J P Pascault.Quantitative DSC Evaluation of Phase Segregation Rate in Linear Segmented Polyurethanes and Polyurethaneureas[J].Polymer Sci,1983,21:415~423.
  • 4[5] N S Schneider,C S Paik Sung. Infrared studies of Hydrogen Bonding in Toluene Diisocyannate based Polyurethanes[J].Macromolucules,1975,8:68~73.
  • 51999-11-11

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