摘要
以磷酸甲酯和乙二醇为原料,通过反应物配比、催化剂用量、反应温度和滴加速度对产率影响的正交试验,优化合成条件,制备一种新型磷酸酯阻燃剂;将其用于棉织物阻燃整理,通过阻燃剂的用量、轧余率、焙烘时间和焙烘温度等整理工艺参数对损毁长度影响的正交试验,优化了整理工艺;采用热分析探讨了阻燃机理.研究结果表明:整理织物损毁长度在105 mm左右,续燃和阴燃时间均为0 s,极限氧指数可达26.4,整理织物阻燃效果可达B1级,能很好满足阻燃织物对阻燃性能的要求.阻燃织物的热分析结果表明该阻燃剂符合磷系阻燃剂凝聚相阻燃机理.
A novel phosphate flame retardant was synthesized with trimethyl phosphate and ethylene.By changing the reactant ratio,the amount of catalyst,reactive temperature and the dropping rate of reactant,the optimized reactive condition was obtained through orthogonal test.Then the cotton fabric was finished by the novel phosphate flame retardant.By changing the amount of flame retardant,up-taking ratio,curing time and curing temperature,the best finishing procedure was obtained and the mechanism of the flame-reta...
出处
《北京服装学院学报（自然科学版）》
CAS
北大核心
2009年第2期41-46,共6页
Journal of Beijing Institute of Fashion Technology：Natural Science Edition
关键词
磷酸甲酯
磷酸酯
阻燃剂
阻燃整理
trimethyl phosphate
phosphate
flame retardant
flame-retardant finishing
