The synthesis and characterization of organometallic copolymers with Mn-Re binuclear transition-metal group in the side chain

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摘要 Novel organometallic copolymers with Mn-Re binuclear transition-metal groups in the side chain are synthesized and characterized.The structure and properties of the copolymers are characterized by GPC,DSC,TG,NMR,FT-IR,UV-Vis spectra and elemental analysis.The glass transition temperature and UV-Vis spectra properties of these three organometallic copolymers are found to be different from the normal polystyrene.New synthetic strategy for the synthesis of or-ganometallic copolymer is developed.

作者 XU Zhi FENG Gang BAI Zhifeng MA Yongqiang CHANG Weixing LI Jing

机构地区 State Key Laboratory of Elemento-Organic Chemistry

出处《Science China Chemistry》 SCIE EI CAS 2006年第5期430-436,共7页 中国科学(化学英文版)

基金 This work was supported by the State Key Laboratory of Polymer Material With Function of Ad-sorption and Extraction.

关键词 TRANSITION-METAL COPOLYMER side chain ORGANOMETALLIC

分类号 N [自然科学总论]

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The synthesis and characterization of organometallic copolymers with Mn-Re binuclear transition-metal group in the side chain

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