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离子液体介质中绿色催化研究新进展 被引量:2

New Advances of Green Catalysis in Ionic liquids Media
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摘要 综述了近年来离子液体在超临界CO2、生物催化、不对称催化3个方面的应用进展,阐明离子液体具有独特的物理化学性质,在许多化工过程中能代替传统的有机溶剂,真正实现环境友好及“绿色催化”,展望了离子液体的发展方向。 Room-temperature ionic liquids,as'designer'green solvents,are attracting more and more attentions because of their remarkable new properties and prospects for 'green'catalysis. And it can be used as environmentally benign media for a range of industrially important chemical processes. New advances of supercritical carbon dioxide,biocatalytic reaction and catalytic asymmetric reaction in ionic liquid media are summarized in this paper.
出处 《江苏化工》 2006年第21期16-20,共5页 Jiangsu Chemical Industry
基金 河南省青年骨干教师资助项目 河南省教育厅自然科学基金资助项目
关键词 离子液体 绿色催化 超临界CO2 生物催化 不对称催化反应 ionic liquid green catalysis supercritical carbon dioxide biocatalysis asymmetric catalytic reaction
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参考文献34

  • 1[1](a)Hagiwara R,Ito Y.Room temperature ionic liquids of alkylimidazolium cations and fluoroanions[J].J Fluorine Chem,2000,105:221-227.(b)Huddleston J G,Visser A E,Reichert W M,et al.Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation[J].Green Chem,2001,3:156-164.
  • 2[2]John S,Wilkes.Properties of ionic liquid solvents for catalysis[J].Journal of Molecular Catalysis A:Chemical,2004,214:11-17.
  • 3[3]Welton T.Room-temperature ionic liquids.solvents for Synthesis and catalysis[J].Chem Rev,1999,99:2 071 -2 083.
  • 4[4]Aki S N V K,Brennecke J F,Samanta A.How polar are room-temperature ionic liquids[J].Chem Commun,2001:413-414.
  • 5[5]Earle M J,Seddon K R.Ionic liquid green solvents for the future[J].Pure Appl Chem,2000,72(7):1 391-1 398.
  • 6[7]Blanchard L A,Gu Z,Brennecke J F.High-pressure phase behavior of ionic liquid/CO2 systems[J].J Phys Chem B,2001,105:2 437-2 444.
  • 7[8]Blanchard L A,Hancu D,Beckman E J,et al.Green processing using ionic liquids and CO2[J].Nature,1999,399:28-29.
  • 8[9]Dzyuba S V,Bartsch R A.Recent advances in applications of room-temperature ionic liquid/supercritical CO2 systems[J].Angew Chem lnt Ed,2003,42(2):148-150.
  • 9[10]Liu F,Abrams M B,Baker R T,et al.Phase-separable catalysis using room temperature ionic liquids and supercritical carbon dioxide[J].Chem Commun,2001:433-434.
  • 10[11]Ballivet-Tkatchenko D,Picquet M,Solinas M,et al.Acrylate dimerisation under ionic liquid-supercritical carbon dioxide conditions[J].Green Chem,2003,5:232-235.

二级参考文献32

  • 1Sheldon R A, Lau R M, Sorgedrager M J, van-Rantwijk F, Seddon K R. Biocatalysis in ionic liquids. Green Chem., 2002,4:147-151.
  • 2Lozano P, de Diego T, Guegan J P, Vaultier M, Iborra J L. Continuous green biocatalytic processes using ionic liquids and supercritical carbon dioxide.Biotechnol. Bioeng.,2001,75:563-569.
  • 3Eckstein M, Sesing M, Kragl U, Adlercreutz P. At low water activity α-chymotrypsin is more active in an ionic liquid than in non-ionic organic solvents.Biotechnol. Lett., 2002,24:867-872.
  • 4Sch(o)fer S H, Kaftzik N, Wasserscheid P, Kragl U. Enzyme catalysis in ionic liquids:lipase catalysed kinetic resolution of 1-phenylethanol with improved enantioselectivity.Chem. Commun.,2001,1: 425-426.
  • 5Park S, Kazlauskas R J. Improved preparation and use of room temperature ionic liquids in lipase-catalyzed enantio- and regioselective acylations.J. Organ. Chem., 2001,66:8395-8401.
  • 6Kim K W, Song B, Choi M Y, Kim M J. Biocatalysis in ionic liquids:markedly enhanced enantioselectivity of lipase. Organ. Lett., 2001,3:1507-1509.
  • 7Lau R M, van-Rantwijk F, Seddon K R, Sheldon R A. Lipase-catalyzed reactions in ionic liquids.Organ.Lett., 2000,2:4189-4191.
  • 8Lozano P, de Diego T, Carrie D, Vaultier M, Iborra J L. Over-stabilization of Candida antarctica lipase B by ionic liquids in ester synthesis. Biotechnol. Lett., 2001,23:1529-1533.
  • 9Itoh T, Akasaki E, Kudo K, Shirakami S. Lipase-catalyzed enantioselective acylation in the ionic liquid solvent system:reaction of enzyme anchored to the solvent.Chem. Lett.,2001,1:262-263.
  • 10Goderis H L, Ampe G, Feyten M P, Fouwe B L, Guffens W M, van Cauwenbergh S M, Tobback P P. Lipase-catalyzed ester exchange reactions in organic media with controlled humidity.Biotechnol. Bioeng.,1986,30:258-266.

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