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SYNTHESIS AND PHOTOPHYSICAL PROPERTIES OF POLY(ARYL IMINO)CONTAINING ACRIDINE UNITS(PAIA)

SYNTHESIS AND PHOTOPHYSICAL PROPERTIES OF POLY(ARYL IMINO) CONTAINING ACRIDINE UNITS(PAIA)
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摘要 1,4-Bis-(4-bromobenzoyl)benzene and proflavine,3,6-diaminoacridine free base were synthesized first.Using 1,4- bis-(4-bromobenzoyl)benzene and proflavine,3,6-diaminoacridine free base as the monomers,poly(aryl imino) containing acridine units(PAIA) was synthesized via palladium-catalyzed amination.The structure of PAIA was characterized by means of FTIR,~1H-NMR spectroscopy and elemental analysis,the results show an agreement with the proposed structure.The UV absorption and photoluminescence spectra were t... 1,4-Bis-(4-bromobenzoyl)benzene and proflavine,3,6-diaminoacridine free base were synthesized first.Using 1,4- bis-(4-bromobenzoyl)benzene and proflavine,3,6-diaminoacridine free base as the monomers,poly(aryl imino) containing acridine units(PAIA) was synthesized via palladium-catalyzed amination.The structure of PAIA was characterized by means of FTIR,~1H-NMR spectroscopy and elemental analysis,the results show an agreement with the proposed structure.The UV absorption and photoluminescence spectra were t...
作者 张林
出处 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2009年第6期851-856,共6页 高分子科学(英文版)
基金 supported by the Foundation of National Key Laboratory of High Temperature and Density Plasma Physics(No.9140C6806030807) the Science and Technology Development Foundation of China Academy of Physics Engineering(No.200708006)
关键词 Poly(aryl imino) Acridine unite Palladium-catalyzed amination PHOTOLUMINESCENCE Poly(aryl imino) Acridine unite Palladium-catalyzed amination Photoluminescence
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参考文献11

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