摘要
The first results of sorption experiments of U(VI), 234U(VI) and 238U(VI) onto original (unpurified) fracture-filling clays from No.1 monzonitic granite intrusion, Beishan area, Gansu Province, China are reported. The monzonitic granite intrusion is a potential location for a high-level radwaste (HLW) repository in China. The present experimental results show that the maximum U(VI) sorption reached 92% at near-neutral pH and the distribution coefficient (Kd) was 1226 mL/g. A high sorption capacity of the fracture-filling clays in host rock on radioactive ele-ments is necessary for HLW deep geological disposal repository. No preferential sorption of 234U onto the clays was found. Finally, the sorption of U(VI) onto the clays was also modeled using a surface complexation model.
The first results of sorption experiments of U(VI), 234U(VI) and 238U(VI) onto original (unpurified) fracture-filling clays from No.1 monzonitic granite intrusion, Beishan area, Gansu Province, China are reported. The monzonitic granite intrusion is a potential location for a high-level radwaste (HLW) repository in China. The present experimental results show that the maximum U(VI) sorption reached 92% at near-neutral pH and the distribution coefficient (Kd) was 1226 mL/g. A high sorption capacity of the fracture-filling clays in host rock on radioactive ele-ments is necessary for HLW deep geological disposal repository. No preferential sorption of 234U onto the clays was found. Finally, the sorption of U(VI) onto the clays was also modeled using a surface complexation model.
作者
MIN Maozhong1,2, LUO Xingzhang3, WANG Ju4, JIN Yuanxin4 & WANG Rucheng1 1. Department of Earth Sciences, State Key Laboratory of Mineral Deposit Research, Nanjing University, Nanjing 210093, China
2. Center of Materials Analysis, Nanjing University, Nanjing 210093, China
3. Department of Environmental Science and Engineering, Nanjing University, Nanjing 210093, China
4. Beijing Geology Institute, Nuclear Industry, Beijing 100029, China
基金
supported by the National Natural Science Foundation of China(Grant Nos.40025209,40173031)
the Ph.D.Base Foundation of Chinese Education Ministry(Grant No.20020284036)
Chinese High-level Radwaste Deep Geologic Disposal Research Foundation.
