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Synthesis of Ag_2S nano-sized clusters and their chemical sensitizations in AgCl cubic and {100} tabular microcrystal imaging systems 被引量:4

Synthesis of Ag_2S nano-sized clusters and their chemical sensitizations in AgCl cubic and {100} tabular microcrystal imaging systems
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摘要 In recent years much attention has been devoted to AgCl emulsion owing to its se-rial advantages and inimitable potential. But in the research of this emulsion a thorny problem remains unsolved till now, which is the improvement in sensitivity is always accompanied with high fog density. In this work 5 nm Ag2S particles were prepared and used as novel sensitizers in AgCl cubic and {100} tabular microcrystal emulsions. The novel sensitizer shows an effective sensitizing ability for silver chloride emulsion, and it is superior to the traditional Na2S2O3 sensi-tizer because by using it comparatively high sensitivity can be obtained with lower fog density. So the above sensitizing problem is going to be effectively solved. To discover the evolution mechanism of the sensitizer clusters and explain their excellent sensitizing properties, diffuse reflectance spectroscopy (DRS) was used as a probe on the AgCl microcrystal surface. In recent years much attention has been devoted to AgCl emulsion owing to its se-rial advantages and inimitable potential. But in the research of this emulsion a thorny problem remains unsolved till now, which is the improvement in sensitivity is always accompanied with high fog density. In this work 5 nm Ag2S particles were prepared and used as novel sensitizers in AgCl cubic and {100} tabular microcrystal emulsions. The novel sensitizer shows an effective sensitizing ability for silver chloride emulsion, and it is superior to the traditional Na2S2O3 sensi-tizer because by using it comparatively high sensitivity can be obtained with lower fog density. So the above sensitizing problem is going to be effectively solved. To discover the evolution mechanism of the sensitizer clusters and explain their excellent sensitizing properties, diffuse reflectance spectroscopy (DRS) was used as a probe on the AgCl microcrystal surface.
出处 《Science China Chemistry》 SCIE EI CAS 2005年第6期516-522,共7页 中国科学(化学英文版)
关键词 SILVER sulfide nano-sized SILVER chloride {100} TABULAR microcrystal chemical sensitization. silver sulfide, nano-sized, silver chloride {100} tabular microcrystal, chemical sensitization.
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