Rapid synthesis of biodegradable poly(epsilon-caprolactone-co-p-dioxanone) random copolymers under microwave irradiation 被引量：4

Rapid synthesis of biodegradable poly(epsilon-caprolactone-co-p-dioxanone) random copolymers under microwave irradiation

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摘要 Biodegradable poly(epsilon-caprolactone-co-p-dioxanone)(PCDO) random copolymers have been synthesized by ring-opening polymerization of epsilon-caprolactone(CL) and p-dioxanone(PDO) under microwave irradiation.The effects of irradiation time and different CL/PDO molar feed ratios on the microwave-assisted ring-opening polymerization(MROP) of PCDO have been discussed.The resultant products were characterized by ~1H NMR,GPC and DSC.It was found that the polymerization was completed within 20 min at 140℃.In th... Biodegradable poly(epsilon-caprolactone-co-p-dioxanone)(PCDO) random copolymers have been synthesized by ring-opening polymerization of epsilon-caprolactone(CL) and p-dioxanone(PDO) under microwave irradiation.The effects of irradiation time and different CL/PDO molar feed ratios on the microwave-assisted ring-opening polymerization(MROP) of PCDO have been discussed.The resultant products were characterized by ~1H NMR,GPC and DSC.It was found that the polymerization was completed within 20 min at 140℃.In th...

作者 Chen, Rui Hao, Jian Yuan Xiong, Cheng Dong Deng, Xian Mo

机构地区 Chinese Acad Sci Univ Elect Sci & Technol China Chinese Acad Sci

出处《Chinese Chemical Letters》 SCIE CAS CSCD 2010年第2期249-252,共4页 中国化学快报（英文版）

关键词 BIODEGRADABLE P-DIOXANONE Microwave irradiation Random copolymer Biodegradable p-Dioxanone Microwave irradiation Random copolymer

分类号 O631.3 [理学—高分子化学]

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参考文献13

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Rapid synthesis of biodegradable poly(epsilon-caprolactone-co-p-dioxanone) random copolymers under microwave irradiation 被引量：4

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