期刊文献+

Electrocatalytic oxidation of methanol at platinum electrode modified with Eu-Fe cyanide-bridged binuclear complexes 被引量:3

Electrocatalytic oxidation of methanol at platinum electrode modified with Eu-Fe cyanide-bridged binuclear complexes
下载PDF
导出
摘要 The electrocatalytic oxidation of methanol at the platinum electrode modified with Eu-Fe cyanide-bridged binuclear complexes (Eu-Fe film) was investigated for the first time by cyclic voltammetry.Compared with the bare platinum electrode,the results showed that the modified electrode had excellent electrocatalytic activity for the oxidation of methanol;the oxidation peak potential shifted more negatively and the peak current increased about twenty times.The electrooxidation of methanol at the modified elect... The electrocatalytic oxidation of methanol at the platinum electrode modified with Eu-Fe cyanide-bridged binuclear complexes (Eu-Fe film) was investigated for the first time by cyclic voltammetry.Compared with the bare platinum electrode,the results showed that the modified electrode had excellent electrocatalytic activity for the oxidation of methanol;the oxidation peak potential shifted more negatively and the peak current increased about twenty times.The electrooxidation of methanol at the modified elect...
机构地区 NW Normal Univ
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2010年第3期337-340,共4页 中国化学快报(英文版)
基金 the Project of Natural Science Foundation of Gansu Province of their financial supports(No. 096RJZA117)
关键词 METHANOL ELECTROCATALYSIS Cyanide-bridged binuclear complexes EUROPIUM Chemically modified electrode Methanol Electrocatalysis Cyanide-bridged binuclear complexes Europium Chemically modified electrode
  • 相关文献

参考文献16

  • 1马永钧,付周周,任小娜,宋青云,周秀英.2,4-二硝基苯酚在类普鲁士蓝修饰电极上的电化学行为及分析应用研究[J].分析化学,2008,36(2):241-244. 被引量:11
  • 2H.S.Liu,C.J.Song,L.Zhang,et al. Journal of Power Sources . 2006
  • 3B.Q.Ma,S.Gao,G.Su,et al. Angewandte Chemie International Edition . 2001
  • 4S.G.Shore,D.W.Knoeppel,H.Deng,et al. J.Alloys.Compd . 1997
  • 5X.Y.Zhou,M.Zhou,Z.Z.Fu,et al. J.Northest Normal Univ.(Nat.Sci.) . 2007
  • 6S.Stevanovic,V.Panic,D.Tripkovic,et al. Electrochemistry Communications . 2009
  • 7Z.L.Liu,X.Y.Ling,X.D.Su,et al. Journal of Physical Chemistry B . 2004
  • 8A.Abbaspour,M.A.Kamyabi. Journal of Electroanalytical Chemistry . 2005
  • 9D.J.Guo,H.L.Li. Journal of Power Sources . 2006
  • 10Yang C,Hu X,Wang D, et al.Ultrasonically treated multi-walled carbon nanotubes (MWCNTs) as PtRu catalyst supports for methanol electrooxidation. Journal of Power Sources . 2006

二级参考文献7

共引文献10

同被引文献21

  • 1Saima Jadoon,Amir Waseem,Mohammad Yaqoob,Abdul Nabi.Flow injection spectrophotometric determination of vitamin E in pharmaceuticals,milk powder and blood serum using potassium ferricyanide-Fe(Ⅲ) detection system[J].Chinese Chemical Letters,2010,21(6):712-715. 被引量:3
  • 2陈玲,王新东,郭敏.Nd_x作为助催化剂对PtRu/C电催化氧化甲醇活性的影响[J].物理化学学报,2006,22(2):141-145. 被引量:13
  • 3MCNICOL B D, RAND D A J, WILLIAAMS K R. Direct methanol-air fuel cells for road transportation [J]. Journal of Power Sources, 1999, 83(1-2): 15-31.
  • 4JAMBUNATHAN K, JAYARAMAN S, HILLIER A C. A multielectrode electrochemical and scanning differential electrochemical mass spectrometry study of methanol oxidation on electrodeposited Ptx Ruy [J]. Langmuir, 2004, 20(5): 1856-1863.
  • 5MACAK J M, BARCZUK P J, TSUCHIYA H, et al. Self-organized nanotubular Ti02 matrix as support for dispersed Pt/Ru nanopartieles : enhancement of the electrocatalytic oxidation of methanol [ J ]. Electrochemistry Communications, 2005, 7(12): 1417-1422.
  • 6LIU Zhao-lin, LING Xing-yi, SU Xiao-di, et al. Carbon-supported Pt and PtRu nanoparticles as catalysts for a direct methanol fuel cell[J]. J Phys Chem B, 2004, 108(24): 8234-8240.
  • 7FREITAS R G, ANTUNES E P, PEREIRA E C. CO and methanol electrooxidation on Pt/Ir/Pt multilayers electrodes [J]. Electrochimica Acta, 2009, 54(7) : 1999-2003.
  • 8ZHOU Xiao-mo, FAN Lou-zhen. Pt/Pd alloy nanoparticles composed of bimetallic nanobowls: Synthesis, characterization and activities[J]. Electrochimca Acta , 8111-8115. electrocatalytic 2010, 55(27).
  • 9HE Bei-bei, DING Dong, XIA Chang-rong. Ni anodes for cells [ J ]. 195(5): 13 La, Ce, Pr, Nd, Sm, Eu, and Gd) cerme intermediate-temperature solid Journal of Power Source 59-1364. oxide rue s, 2010.
  • 10TANASE S, REEDIJK J. Chemistry and magnetism of cyanido-bridged d-f assemblies[J]. Coordination Chemistry Reviews, 2006, 250(19-20): 2501-2510.

引证文献3

二级引证文献6

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部