期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

高压诱致的反式联苯乙烯酮结构相变与化学反应

High Pressure Induced Phase Transitions and Chemical Reaction of Trans,Trans-Dibenzylideneacetone
下载PDF
导出
摘要 利用金刚石对顶砧(DAC)高压装置在室温下对反式联苯乙烯酮(Trans,Trans-Dibenzylideneacetone)分子晶体进行了高压拉曼谱、荧光光谱和能量色散X射线衍射(EDXRD)研究。结果表明,在压力为1.0～1.3 GPa时,反式联苯乙烯酮发生了晶体—晶体的结构相变,同时开始伴随有压力诱导的化学反应,反应完成的压力为6.5 GPa。高压X射线研究表明,这次相变有新的共价键产生,可能的化学变化过程是,C C双键打开再与相邻的分子结合生成新的共价键。在压力大约为11 GPa时,反式联苯乙烯酮分子晶体再次发生了晶体的结构相变。新产生的物质在卸压后依然保持稳定。 By using a diamond anvil cell the trans,trans-Dibenzylideneacetone molecular crystal was studied with high pressure Raman,fluorescence spectroscopy and EDXRD at room temperature.A crystalline to crystalline phase transition is found at 1.0~1.3 GPa;meanwhile,a pressure induced chemical reaction is observed and the reaction is completed around 6.5 GPa.The EDXRD spectra show that a new covalent bond produces in this chemcial reaction process.The possible chemical reaction paths are suggested as the openning of...
作者 唐旭东 张增明 赵智 王中平 丁泽军
机构地区 中国科技大学物理系合肥微尺度物质科学国家实验室
出处 《高压物理学报》 EI CAS CSCD 北大核心 2009年第6期401-406,共6页 Chinese Journal of High Pressure Physics
基金 国家自然科学基金(10874160) 教育部博士点基金
关键词 反式联苯乙烯酮 高压 拉曼 能量色散X射线衍射 相变 trans trans-dibenzylideneacetone high pressure Raman spectra EDXRD phase transition
分类号 O521.21 [理学—高压高温物理]
  • 相关文献

参考文献1

二级参考文献23

  • 1Edwards C M, Butler I S. Pressure-Tuning Spectroscopy of Inorganic Compounds: A Summary of the Past 15 Years [J]. Coordination Chem Rev,2000,199(1) :1-153.
  • 2von Doering E W, Birladeanu L, Sarma K, et al. Perturbation of the Degenerate,Concerted Cope Rearrangement by Two Phenyl Groups in Active Positions of (E)-1,4-Diphenylhexa-1,5-Diene. Acceleration by High Pressure as Criterion of Cyclic Transition States [J]. J Am Chem Soc,1994,116(10) :4289-4297.
  • 3Klaerner F-G,Krawczyk Bernd,Ruster V,et al. Evidence for Pericyclic and Stepwise Processes in the Cyclodimerization of Chloroprene and 1,3-Butadiene from Pressure Dependence and Stereochemistry. Experimental and Theoretical Volumes of Activation and Reaction [J]. J Am Chem Soc, 1994,116(17) :7646-7657.
  • 4Diedrich M K,Klarner F-G. The Effect of Pressure on Cyclizations. The Ring-Size Dependent Reaction Volumes of the Cyclization of 1-Alkenes to Cycloalkanes. Experimental Measurement of Activation and Reaction Volumes of the Intramolecular Diels-Alder Reaction of 1,3,8-Nonatriene and 1,3,9-Decatrien'e. Temperature Dependence of Activation and Reaction Volumes [J]. J Am Chem Soc, 1998,120(25):6212-6218.
  • 5Sugihara T,Takebayashi M,Kaneko C. Effects of High Pressure on the Heck Reaction. Is It Possible to Control Dehydropalladation of Alkylpalladium Intermediates Having β-Hydrogens? [J]. Tetrahedron Letters, 1995,36(31) : 5547-5550.
  • 6Kotsuki H, Teraguchi M, Shimomoto N, et al. Ytterbium(Ⅲ) Trifluoromethanesulfonate Catalyzed High Pressure Reaction of Epoxides with Indole. An Enantioselective Synthesis of (+)-Diolmycin A2 [J]. Tetrahedron Letters, 1996,37(21) :3727-3730.
  • 7Teixeira A M R,Freire P T C,Moreno A J D,et al. High-Pressure Raman Study of L-Alanine Crystal [J]. Solid State Commun, 2000,116 (7) : 405-409.
  • 8Lothar S, Albert W. Phase Behaviour of Cyclohexane-d12 at Pressure up to 300 MPa and Temperatures between 170 and 300 K [J]. J Chem Thermodynamics, 1987,19 : 363-368.
  • 9Crain J,Poon W C-K,Cainrs-Smith A,et al. High-Pressure Raman Spectroscopic Study of Cyclohexane C6H12 and C6D12[J]. J Phys Chem,1992,96:8168-8173.
  • 10Pravica Michael G, Shen Y, Nicol Malcolm F. High Pressure Raman Spectroscopic Study of Structural Polymorphism in Cyclohexane [J]. Appl Phys Lett,2004,84:5452-5454.

共引文献1

高压物理学报
2009年 第6期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部