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Effects of volume fraction condition on thermodynamic restrictions in mixture theory

Effects of volume fraction condition on thermodynamic restrictions in mixture theory
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摘要 Volume fraction condition is a true constraint that must be taken into consideration in deducing the thermodynamic restrictions of mixture theory applying the axiom of dissipation. For a process to be admissible, the constraints imposed by the volume fraction condition include not only the equation obtained by taking its material derivative with respect to the motion of a given phase, but also those by taking its spatial gradient. The thermodynamic restrictions are deduced under the complete constraints, the results obtained are consistent for the mixtures with or without a compressible phase,and in which the free energy of each phase depends on the densities of all phases. Volume fraction condition is a true constraint that must be taken into consideration in deducing the thermodynamic restrictions of mixture theory applying the axiom of dissipation. For a process to be admissible, the constraints imposed by the volume fraction condition include not only the equation obtained by taking its material derivative with respect to the motion of a given phase, but also those by taking its spatial gradient. The thermodynamic restrictions are deduced under the complete constraints, the results obtained are consistent for the mixtures with or without a compressible phase, and in which the free energy of each phase depends on the densities of all phases.
出处 《Science China Mathematics》 SCIE 2002年第5期640-647,共8页 中国科学:数学(英文版)
基金 This work was supported by the Knowledge Innovation Foundation of Chinese Academy of Sciences.
关键词 MIXTURE theory VOLUME FRACTION condition THERMODYNAMIC restrictions. mixture theory volume fraction condition thermodynamic restrictions
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