摘要
Copolymers which are synthesized by oligomers or homopolymers have quasi-one-dimen sional structures. A tight-binding model was suggested to study the organic quantum-well properties of triblock copolymers xPA/nPPP/yPA and xPPP/nPA/yPPP consisting of polyacetylene (PA) and poly(p-phenylene) (PPP). It was found that the electronic density in the lowest conductive state ( LU MO) could be tuned by the ratios of homopolymers and interfacial coupling. The spontaneous quantum tunneling effects will occur in triblock copolymer xPA/nPPP/yPA with the increasing interfacial cou pling.
Copolymers which are synthesized by oligomers or homopolymers have quasi-one-dimensional structures. A tight-binding model was suggested to study the organic quantum-well properties of triblock copolymers xPA/nPPP/yPA and xPPP/nPA/yPPP consisting of polyacetylene (PA) and poly( p-phenylene) (PPP). It was found that the electronic density in the lowest conductive state (LUMO) could be tuned by the ratios of homopolymers and interfacial coupling. The spontaneous quantum tunneling effects will occur in triblock copolymer xPA/nPPP/yPA with the increasing interfacial coupling.
基金
This work was supported by the National Natural Science Foundation of China ( Grant Nos. 10074040 and 59871024).
