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Hydrogen Bonding in Thermoplastic Polyurethane Elastomers:IR Thermal Analysis

Hydrogen Bonding in Thermoplastic Polyurethane Elastomers:IR Thermal Analysis
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摘要 The hydrogen bond percentage and its temperature dependence of the three TPU samples synthesized from polytetrahydrofuran, 4,4'-diphenylmethane diisocyanate, N -methyl diethanol amine or 1,4-butane diol were studied by means of IR thermal analysis. The enthalpy and the entropy of the hydrogen bond dissociation were determined by the Van't Hoff plot. The hydrogen bond percentage and its temperature dependence of the three TPU samples synthesized from polytetrahydrofuran, 4,4'-diphenylmethane diisocyanate, N -methyl diethanol amine or 1,4-butane diol were studied by means of IR thermal analysis. The enthalpy and the entropy of the hydrogen bond dissociation were determined by the Van't Hoff plot.
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2002年第1期84-87,共4页 高等学校化学研究(英文版)
基金 Supported by the Key Subject Construction Project of Shanghai Educational Com mittee(No. 13980 70 2 )
关键词 Thermoplastic polyurethane elastomers IR thermal analysis HYDROGEN Bond effect Thermoplastic polyurethane elastomers IR thermal analysis Hydrogen Bond effect
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