摘要
The one plus one (1 + 1) mode of hydrosilation reaction of ladderlike cis-isotatic polyallylsilsesquioxane (Allyl-T) and polyhydrosilsesquioxane (H-T) using dicyclopentadienylplatinumdichloride (Cp2PtCl2) as the catalyst leads to the formation of a new polyorganosiloxane (POS). The presence of nanoscale tubular structure in the product POS was preliminarily proved by IR, H-1-NMR, differential scanning calorimetry (DSC), X-ray diffraction (XRD), gel permeation chromatography (GPC), atomic force microscopy (AFM) and molecular simulation.
The one plus one (1 + 1) mode of hydrosilation reaction of ladderlike cis-isotatic polyallylsilsesquioxane (Allyl-T) and polyhydrosilsesquioxane (H-T) using dicyclopentadienylplatinumdichloride (Cp2PtCl2) as the catalyst leads to the formation of a new polyorganosiloxane (POS). The presence of nanoscale tubular structure in the product POS was preliminarily proved by IR, H-1-NMR, differential scanning calorimetry (DSC), X-ray diffraction (XRD), gel permeation chromatography (GPC), atomic force microscopy (AFM) and molecular simulation.
基金
This project was supported by the National Natural Science Foundation of China (No. 59483001).
