摘要
A new heat-resistant, soluble polymer, poly(phenyl-1,2,4-triazine imide), has been prepared via a two-step method of polycondensation of N,N'-bis(4-benzil)pyromellitimide and terephthalamidrazone in cresol, followed by curing at higher temperature. The rigid 1,2,4-triazine group increases the solubility of the polyimide so that the polymer is soluble in cresol, N-methyl-2-pyrrolidone (NMP), trifluoroacetic acid and concentrated sulfuric acid, etc. Thermogravimetric analysis (TGA) indicates that this novel polyimide has good thermal stability with a high decomposition temperature of 447degreesC in air and of 423 degreesC in N-2, It has a tensile strength of 107.4 MI'a with an elongation at break of around 7.6%.
A new heat-resistant, soluble polymer, poly(phenyl-1,2,4-triazine imide), has been prepared via a two-step method of polycondensation of N,N'-bis(4-benzil)pyromellitimide and terephthalamidrazone in cresol, followed by curing at higher temperature. The rigid 1,2,4-triazine group increases the solubility of the polyimide so that the polymer is soluble in cresol, N-methyl-2-pyrrolidone (NMP), trifluoroacetic acid and concentrated sulfuric acid, etc. Thermogravimetric analysis (TGA) indicates that this novel polyimide has good thermal stability with a high decomposition temperature of 447degreesC in air and of 423 degreesC in N-2, It has a tensile strength of 107.4 MI'a with an elongation at break of around 7.6%.
基金
This project was supported by the National Natural Science Foundation of China (Grant No. 29773024).
