摘要
Electrochemical impedance spectroscopy (EIS) was first used for the characterization of polyfuran (PFu) films that had been formed electrochemically on an Au electrode. The polyfuran was measured in high oxidation state, intermediate oxidation state and reduction state, respectively. As the oxidation level is increased, the ionic conductivity of PFu/BF4- increases. And impedance studies on PFu show that the anion BF4- appears to be mobile with a high diffusion coefficient of approximately 10(-8) cm(2).s(-1).
Electrochemical impedance spectroscopy (EIS) was first used for the characterization of polyfuran (PFu) films that had been formed electrochemically on an Au electrode. The polyfuran was measured in high oxidation state, intermediate oxidation state and reduction state, respectively. As the oxidation level is increased, the ionic conductivity of PFu/BF4- increases. And impedance studies on PFu show that the anion BF4- appears to be mobile with a high diffusion coefficient of approximately 10(-8) cm(2).s(-1).
基金
This work was supported by the National Natural Science Foundation of China (No. 50133010).
