摘要
A new method for preparing LiLaNiO/γ(-Al2O3 monolithic catalyst was described and discussed. The catalyst, which was supported over the monolith, was evaluated in a POM to syngas process. Relative stable catalytic properties during the 120 hours operation at atmospheric pressure were found for the catalyst. Under the high space velocity of 9.0×104l/(kg·(h)(CH4), the conversion of methane came to 95.5%, and the selectivity of carbon monoxide was not below 96.0% at 1123K when ratio of the feedstock (CH4/O2) was equal to 2.0.
基金
the National Advanced Materials Committee of China (Grant No. 715-006-0122) and the Ministry of Science and Technology, China (