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A Study on Production of Carbon Nanotubes by CH_4 Decomposition over LaNiO_3,La_4Ni_3O_(10),La_3Ni_2O_7 and La_2NiO_4

A Study on Production of Carbon Nanotubes by CH_4 Decomposition over LaNiO_3,La_4Ni_3O_(10),La_3Ni_2O_7 and La_2NiO_4
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摘要 Carbon nanotubes (CNTs) of narrow size distribution can be abundantly produced in the catalytic decomposition of CH4 over pre-reduced LaNiO3, La4Ni3O10, La3Ni2O7 and La2NiO4. The CNTs obtained were characterized by means of transmission electron microscopy (TEM). Thermal oxidation of CNTs in air was monitored thermogravimetrically (TG). The results revealed that a lower La/Ni ratio of the catalysts would lead to a wider diameter distribution and a higher degree of graphitic nature. Carbon nanotubes (CNTs) of narrow size distribution can be abundantly produced in the catalytic decomposition of CH4 over pre-reduced LaNiO3, La4Ni3O10, La3Ni2O7 and La2NiO4. The CNTs obtained were characterized by means of transmission electron microscopy (TEM). Thermal oxidation of CNTs in air was monitored thermogravimetrically (TG). The results revealed that a lower La/Ni ratio of the catalysts would lead to a wider diameter distribution and a higher degree of graphitic nature.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2001年第9期839-842,共4页 中国化学快报(英文版)
关键词 Carbon nanotubes LANIO3 La2NiO4 La3Ni2O7 La4Ni3O10 CH4 Carbon nanotubes LaNiO3 La2NiO4 La3Ni2O7 La4Ni3O10 CH4
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