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Photoisomerization of the Graft Copolymer of Starch and Azo-dye

Photoisomerization of the Graft Copolymer of Starch and Azo-dye
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摘要 Optical data storage materials are mainly based on organic molecules. To be suited for as an optical data storage material, molecules have to be photochromatic, they must be capable of being reversibly switched be. tween two spectroscopically distinct forms by use of light[1].Photoisome rization (trans ~cis) of azoaromatic compounds has been investigated extensively using UV-Vis spectroscopy. In 1972[2], the isomerization of various azobenzenes bound on the side chain or within the main chain of poly (methyl methacrylate), poly(ethyl methacrylate),polystyrene, a polyamide, and polyester had. been demonstrated. There are three processes: a trans-cis photochemical isomerization, a cis-trans photochemical isomerization, and a cis-trans thermal isomerization, which occurs due to the higher stability of the trans configuration, since that pioneering study, two main directions of research developed and are very active in the eurrent literature.
作者 FU ZhengSheng
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2001年第z1期97-98,共2页 高等学校化学研究(英文版)
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