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叠氮和1-(4-吡啶基)-2-(2-苯甲氰基)乙烯锌(Ⅱ)配合物的合成与晶体结构(英文)

The Synthesis and Crystal Structure of a Zn(Ⅱ) Complex with Azideand 1-(4-Pyridyl)-2-(2-cyanobenzene) Ethylene
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摘要 The hydrothermal reaction of Zn(NO3)2, NaN3, and 1-(4-pyridyl)-2-(2-cyanobenzene) ethylene (PCE), at the mole ratio 1∶2∶2 in methanol and water at 70 ℃ for two days afforded [Zn(PCE)2(N3)2], the structure of which features a four-coordinated distorted tetrahedron geometry around zinc(Ⅱ). CCDC: 235945. The hydrothermal reaction of Zn(NO3)2, NaN3, and 1-(4-pyridyl)-2-(2-cyanobenzene) ethylene (PCE), at the mole ratio 1∶2∶2 in methanol and water at 70 ℃ for two days afforded [Zn(PCE)2(N3)2], the structure of which features a four-coordinated distorted tetrahedron geometry around zinc(Ⅱ). CCDC: 235945.
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2004年第8期1005-1006,共2页 Chinese Journal of Inorganic Chemistry
基金 国家重点发展规划资助项目(No.G2000077500) 国家自然科学基金资助项目(No.20028101)。
关键词 叠氮 1-(4-吡啶基)-2-(2-苯甲氰基)乙烯 锌配合物 合成 晶体结构 azide zinc complex crystal structure
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